Abstract
The frequency-pulse method is used to measure the speed of sound in ethyl and methyl alcohols at atmospheric pressure over the temperature range 293–351°K. Values of isochoric heat capacity and coefficients of adiabatic and isothermal expansion of methyl alcohol at atmospheric pressure are calculated for the pressure range 175.47–337.85°K.
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Abbreviations
- T:
-
temperature
- v:
-
specific volume
- W:
-
velocity of sound
- CV, CP :
-
isochoric and isobaric heat
- βS, βT :
-
adibatic and isothermal contraction coefficients
- α:
-
coefficient of thermal expansion
Literature cited
E. B. Freyer, J. C. Hubbard, and D. H. Andrews, “Sonic studies of the physical properties of liquids. The sonic interferometer. The velocity of sound in some organic liquids and their compressibilities,” J. Am. Chem. Soc.,51, No. 3, 759–770 (1929).
W. Wilson and D. Bradley, “Speed of sound in four primary alcohols as a function of temperature and pressure,” J. Acoust. Soc. Am.,36, No. 2, 333–337 (1964).
O. Z. Golik, Yu. I. Shimanskii, and I. M. Kobiichuk, “Compressibility of isoviscous materials,” Ukr. Fiz. Zh.,3. No. 4, 537–541 (1958).
W. D. T. Dale, P. A. Flavelle, and P. Kruus, “Concentration fluctuations in water-methanol mixtures as studied by ultrasonic absorption,” Can. J. Chem., No. 3, 355–366 (1976).
J. Emery, S. Gasse, R. A. Pethrick, and D. W. Phillips, “Ultrasonic studies of molecular relaxation in pure alcohols,” Adv. Mol. Relax. Int. Processes,12, No. 1, 47–64 (1978).
U. Sh. Gadaibaev and M. I. Shakhparonov, “Acoustical relaxation in methanol-N-hexanol solutions,” Akust. Zh.,19, 1865–1866 (1973).
H. Nomura, T. Banba, and Y. Miyanara, “Pressure and temperature dependence of the sound velocities of methanol-carbon tetrafluoride mixtures,” J. Acoust. Soc. Jpn.,30, No. 4, 228–231 (1974).
A. Weissler, “Ultrasonic investigation of molecular properties of liquids. II. The alcohols,” J. Am. Chem. Soc.,70, No. 4, 1634–1640 (1948).
E. H. Carnevale and T. A. Litovitz, “Pressure dependence of sound propagation in the primary alcohols,” J. Acoust. Soc. Am.,27, No. 3, 547–550 (1955).
S. K. Kor, O. N. Awasthi, G. Rai, and S. C. Deorani, “Structural absorption of ultrasonic waves in methanol,” Phys. Rev. A.,3, No. 1, 390–393 (1971).
V. M. Merkulova and V. A. Tret'yakov, “Effect of multiple resonance in quartz transducers on precision measurements of ultrasound speed and attenuation,” Akust. Zh.,22, No. 3, 412–415 (1976).
V. S. Kononenko, “Diffraction correction formulas for ultrasound measurements,” Akust. Zh.,20, No. 2, 269–273 (1974).
D. K. Larkin, Author's Abstract of Candidate's Dissertation, Moscow Engineering Institute, Moscow (1976).
A. A. Aleksandrov, “Experimental study of the speed of sound in ethyl alcohol at temperatures of 265–503°K and pressures to 100 MPa,” No. B 664558, Moscow (1978), p. 40.
R. C. Wilhoit and B. J. Zwolinski, “Physical and thermodynamic properties of aliphatic alcohols,” J. Phys. Chem. Ref. Data,2, No. 1, 44–55 (1973).
V. N. Zubarev, P. G. Prusakov, and L. V. Sergeeva, Thermophysical Properties of Methyl Alcohol [in Russian], Standartov, Moscow (1973), pp. 9–16.
D. Tyrer, “Adiabatic and isothermal compressibilities of liquid between one-two atmospheres pressure,” J. Chem. Soc. Trans.,105, 2534–2553 (1914).
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Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 42, No. 1, pp. 92–98, January, 1982.
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Aleksandrov, A.A., Khasanshin, T.S. & Kosoi, D.S. Speed of sound, isochoric heat capacity, and coefficients of adiabatic and isothermal expansion in methyl alcohol at atmospheric pressure. Journal of Engineering Physics 42, 76–81 (1982). https://doi.org/10.1007/BF00824996
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DOI: https://doi.org/10.1007/BF00824996