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Synthese und Geruch von (E)- und (Z)-bis-homo-ß-Santalol

Synthesis and odour of (E)- and (Z)-bis-homo-ß-santalol

  • Organische Chemie Und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The synthesis of the title compounds is described. Guided by theoretical considerations and molecular modeling studies, the influence of the bulky group opposite to the osmophorically important primary hydroxyl function on the odour impression is determined. The organoleptic evaluation proved the predicted sandal like odour of the (Z)-isomer and its also predicted absence with (E)-isomer. A moderate increase of the volume of the bulky group shows no influence on the sandalwood odour of the new analogue.

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Authors and Affiliations

  1. Institut für Pharmazeutische Chemie, Universität Wien, A-1090, Wien, Österreich

    G. Buchbauer, H. Spreitzer, F. Zechmeister-Machhart, C. Haunschmidt & F. Tröscher

Authors
  1. G. Buchbauer
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  2. H. Spreitzer
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  3. F. Zechmeister-Machhart
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  4. C. Haunschmidt
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  5. F. Tröscher
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Buchbauer, G., Spreitzer, H., Zechmeister-Machhart, F. et al. Synthese und Geruch von (E)- und (Z)-bis-homo-ß-Santalol. Monatsh Chem 127, 747–753 (1996). https://doi.org/10.1007/BF00817266

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  • DOI: https://doi.org/10.1007/BF00817266

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