Summary
The acetale-ketone9 was synthesized as precursor for the preparation of β-santalol derivatives posessing a bicyclo[2.2.2]octane nucleus. After methylenation of the keto-group the subsequent acidic hydrolysis of the acetal leads via a Prins reaction of the liberated aldehyde with the methylene group to tricyclo[6.2.2.02, 7]dodecane derivatives. Their olfactory properties are described.
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Spreitzer, H. Synthese und Geruch von Tricyclo[6.2.2.02, 7]dodecan-Derivaten. Monatsh Chem 123, 593–597 (1992). https://doi.org/10.1007/BF00816854
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DOI: https://doi.org/10.1007/BF00816854