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Thio-analogues of 2-(1H-Heteroarylidene)-1H-indene-1,3(2H)-diones, synthesis and formation of metal complexes

Thio-Analoge von 2-(1H-Heteroaryliden)-1H-inden-1,3(2H)-dionen. Synthese und Bildung von Metallkomplexen

  • Organische Chemie und Biochemie
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Abstract

2-(1H-Heteroarylidene)-1H-indene-1,3(2H)-diones were converted into anils and dianils and then into monothio- and dithio-derivatives by treatment with hydrogen sulphide. The 2-pyridinyl monothioderivate was converted into S-alkyl ethers. In contrast with the dione1 the thio-derivatives readily formed isolable complexes with transition metals. Spectroscopic and magnetic data are reported.

Zusammenfassung

2-(1H-Heteroaryliden)-1H-inden-1,3(2 H)-dione wurden in Anile und Dianile und durch anschließende Behandlung mit Schwefelwasserstoff in die entsprechenden Mono- und Di-thio-derivate umgewandelt. Aus den 2-Pyridinyl-monothio-derivaten wurdenS-Alkyl-ether erhalten. Im Gegensatz zum Dion1 bildeten die Thioderivate glatt isolierbare Komplexe mit Übergangsmetallen. Spektroskopische und magnetische Daten werden mitgeteilt.

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Authors and Affiliations

  1. Department of Chemistry, University College, Dublin 4, Ireland

    Katherine Buggle, William K. Glass, Michael Nangle & Joseph Power

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  1. Katherine Buggle
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  2. William K. Glass
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  3. Michael Nangle
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  4. Joseph Power
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Buggle, K., Glass, W.K., Nangle, M. et al. Thio-analogues of 2-(1H-Heteroarylidene)-1H-indene-1,3(2H)-diones, synthesis and formation of metal complexes. Monatsh Chem 113, 81–90 (1982). https://doi.org/10.1007/BF00814340

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  • DOI: https://doi.org/10.1007/BF00814340

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