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Solvatochromism of thiocyanato-tetraazamacrocycle-manganese(III) complexes

Solvatochromie von Thiocyanato-Tetraazamakrocyclo-Mangan(III) — Komplexen

  • Anorganische Und Physikalische Chemie
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Summary

Solvent effects on thecharge-transfer bands of a series of thiocyanato-tetraazamacrocycle-manganese(III) complexes are reported, and discussed in terms of the donor and acceptor (hydrogen-bonding) properties of the respective solvents. The piezochromic behaviour of one of these complexes is also described.

Zusammenfassung

Die Auswirkung von Lösungsmitteleffekten auf diecharge-transfer — Banden einer Reihe von Thiocyanato-Tetraazamakrocyclo-Mangan(III) — Komplexen wird im Zusammenhang mit den Donor- und Akzeptoreigenschaften des Lösungsmittels diskutiert. Das piezochrome Verhalten eines der Komplexe wird beschrieben.

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Authors and Affiliations

  1. Chemistry Department, University of Leicester, LE1 7RH, Leicester, United Kingdom

    J. Burgess, D. L. Davies, A. J. Grist, J. A. Hall & S. A. Parsons

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  1. J. Burgess
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  2. D. L. Davies
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  3. A. J. Grist
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  4. J. A. Hall
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  5. S. A. Parsons
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Burgess, J., Davies, D.L., Grist, A.J. et al. Solvatochromism of thiocyanato-tetraazamacrocycle-manganese(III) complexes. Monatsh Chem 125, 515–523 (1994). https://doi.org/10.1007/BF00811843

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  • DOI: https://doi.org/10.1007/BF00811843

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