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Die Bindungsverhältnisse in der Clusterverbindung CZr6I14

The bonds in the cluster compound CZr6I14

  • Anorganische Und Physikalische Chemie
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Summary

The electronic properties of the cluster compound CZr6I14 are discussed on the basis of EHT results. In the model cluster CZr6I 4−18 the calculated Zr-Zr distance in the metal octahedron is enlarged by encapsulation of the interstitial C as well as by the surrounding ligands. The interstitial bond is realized by the two bond orbitals a1g, t1u, and, additional, by three t1u orbitals of the 5 p(I) band. The Zr-Zr bonds are week. The cluster CZr6I 4−18 is held together by strong C-Zr and Zr-I bonds.

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Literatur

  1. Smith J. D., Corbett J. D. (1985) J. Am. Chem. Soc.107: 5704; (1986) J. Am. Chem. Soc.108: 1927

    Google Scholar 

  2. Hughbanks T., Rosenthal G., Corbett J. D. (1986) J. Am. Chem. Soc.108: 8289; (1988) J. Am. Chem. Soc.110: 1511

    Google Scholar 

  3. Ziebarth R. P., Corbett J. D. (1989) J. Am. Chem. Soc.111: 3272

    Google Scholar 

  4. Hughbanks T., Corbett J. D. (1989) Inorg. Chem.28: 631

    Google Scholar 

  5. Simon A. (1988) Angew. Chemie100: 163

    Google Scholar 

  6. Künne L., Fritsche H.-G. (1990) J. Less-Common Met.160: 295

    Google Scholar 

  7. Künne L. D., Fritsche H.-G., Almasri Z. (1990) Monatsh. Chem.121: 493

    Google Scholar 

  8. Künne L., Almasri Z. (1990) J. Less-Common Met.161: 321

    Google Scholar 

  9. Künne L., Almasri Z. (1990) J. Less-Common Met.166: 386

    Google Scholar 

  10. Künne L., Fritsche H.-G. (1988) Monatsh. Chem.119: 1365

    Google Scholar 

  11. Herman F., Skillman S. (1963) Atomic Structure Calculations. Prentice-Hall, Englewood Cliffs

    Google Scholar 

  12. Slater J. C. (1974) Quantum Theory of Molecules and Solids, Vol. 4. McGraw-Hill, New York

    Google Scholar 

  13. Basch H., Viste A., Gray H. B. (1965) Theor. Chim. Acta (Berlin)3: 456

    Google Scholar 

  14. Moore B. Ch. (1948) Atomic Energy Levels. U.S. Government Printing Office, Washington

    Google Scholar 

  15. Clementi E., Raimondi D. L. (1963) J. Chem. Phys.38: 2686

    Google Scholar 

  16. Clementi E., Raimondi D. L., Reinhart W. P. (1967) J. Chem. Phys.47: 1300

    Google Scholar 

  17. Saillard J.-Y., Hoffmann R. (1984) J. Am. Chem. Soc.106: 2006

    Google Scholar 

  18. Hofmann P., Stauffert P., Schore N. E. (1982) Chem. Ber.115: 2153

    Google Scholar 

  19. Anders L. W., Hansen R. S., Bartell L. S. (1973) J. Chem. Phys.59: 5277

    Google Scholar 

  20. Skala L., Künne L., Fritsche H.-G., Müller H. (1982) Phys. Stat. Sol. (b)114: 439

    Google Scholar 

  21. Opitz Ch., Grünler B., Müller H. (1986) J. Less-Common Met.128: 73; (1988) J. Less-Common Met.144: 257

    Google Scholar 

  22. Müller H., Führ U., Opitz Ch., Fritsche H.-G. (1988) J. Less-Common Met.137: 195

    Google Scholar 

Download references

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Friedrich-Schiller-Universität Jena, Am Steiger 3, Haus 3, D-O-6900, Jena, Bundesrepublik Deutschland

    Lutz Dieter Künne

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  1. Lutz Dieter Künne
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Dieter Künne, L. Die Bindungsverhältnisse in der Clusterverbindung CZr6I14 . Monatsh Chem 122, 625–633 (1991). https://doi.org/10.1007/BF00811461

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  • DOI: https://doi.org/10.1007/BF00811461

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