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Synthesis and spectroscopic studies of Sb(III) and Bi(III) complexes of semicarbazones

Synthese und spektroskopische Untersuchungen von Sb(III)- und Bi(III)-Komplexen mit Semlcarbazonen

  • Anorganische Und Physikalische Chemie
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Summary

New complexes of Sb(III) and Bi(III) with semicarbazones of the general formulae SbCl3 L and BiCl3 L (whereL=semicarbazones) have been prepared and characterized by IR,1H- and13C-NMR spectral measurements. The results of the spectroscopic studies indicate that the semicarbazone ligands act as bidentate in all the complexes. All complexes are non-electrolytes inDMF solution. The molecular weight determinations indicate that the compounds are monomeric.

Zusammenfassung

Es wurden neue Komplexe von Sb(III) und Bi(III) mit Semicarbazonen von der allgemeinen Formel SbCl3 L und BiCl3 L (L=verschiedenene Semicarbazone) dargestellt und mittels IR,1H- und13C-NMR charakterisiert. Die spektroskopischen Untersuchungen zeigten, daß die Semicarbazon-Liganden in allen Komplexen zweizähnig agieren. Molekulargewichtsbestimmungen zeigten die monomere Natur der Verbindungen an.

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Authors and Affiliations

  1. Department of Chemistry, Kurukshetra University, 132 119, Kurukshetra, India

    Kiran Singh

  2. Department of Chemistry, University of Rajasthan, 302 004, Jaipur, India

    J. P. Tandon

Authors
  1. Kiran Singh
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  2. J. P. Tandon
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Singh, K., Tandon, J.P. Synthesis and spectroscopic studies of Sb(III) and Bi(III) complexes of semicarbazones. Monatsh Chem 123, 983–986 (1992). https://doi.org/10.1007/BF00810928

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  • DOI: https://doi.org/10.1007/BF00810928

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