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[Cl3Cu(I)-As(III)O3]: Ein kristallchemisch neues Bauelement in der Struktur des Pb6Cu(AsO3)2Cl7

[Cl3Cu(I)-As(III)O3]: A novel structural element in crystal chemistry within the structure of Pb6Cu(AsO3)2Cl7

  • Anorganische Und Physikalische Chemie
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Abstract

The synthetic compound Pb6Cu(AsO3)2Cl7 crystallizes in space group R\(\bar 3\) witha 0=9.8614(4),c 0=17.089(2)Å,Z=3. The crystal structure, determined by single crystal X-ray work, is a typical layer structure. Complex Pb6(AsO3)2Cl6 layers are combined via monovalent Cu and Cl atoms. A novel element within the structure is a [Cl3Cu(I)-As(III)O3] group with the interatomic distances (Å): Cu-Cl=2.44 (3×), As-O=1.76 (3×), Cu-As=2.34 (1×).

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Authors and Affiliations

  1. Institut für Mineralogie und Kristallographie, Universität Wien, A-1010, Wien, Österreich

    Franz Pertlik

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  1. Franz Pertlik
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Pertlik, F. [Cl3Cu(I)-As(III)O3]: Ein kristallchemisch neues Bauelement in der Struktur des Pb6Cu(AsO3)2Cl7 . Monatsh Chem 117, 1257–1261 (1986). https://doi.org/10.1007/BF00810870

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  • DOI: https://doi.org/10.1007/BF00810870

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