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On the reaction of dithiocarbamates with nitrogen-containing derivates of oxalic acid

Zur Reaktion von Dithiocarbaminaten mit stickstoffhaltigen Derivaten der Oxalsäure

  • Organische Chemie Und Biochemie
  • Published:
Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Summary

The action of bisimidochlorides of oxalic acid on dithiocarbamates produces 2-thioxo-3-aryl(alkyl)-4,5-diiminothiazolidines by cycloacylation. The molecular structure of 2-thioxo-3-(4-methoxyphenyl)-4,5-bis(phenylimino)-thiazolidine is confirmed by X-ray crystal structure analysis.

Zusammenfassung

Bei der Einwirkung von Bisimidchloriden der Oxalsäure auf Dithiocarbaminate entstehen durch Cycloacylierung 2-Thioxo-3-aryl(alkyl)-4,5-diiminothiazolidine. Die Molekülstruktur von 2-Thioxo-3-(4-methoxyphenyl)-4,5-bis(phenylimino)thiazolidin wird durch Röntgenkristallstrukturanalyse bestätigt.

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Authors and Affiliations

  1. Central Research Institute for Chemistry, Hungarian Academy of Science, P.O. Box 17, H-1525, Budapest, Hungary

    Vilmos Fülöp & Alajos Kalman

  2. Sektion Chemie, Friedrich-Schiller-Universität Jena, DDR-6900, Jena, German Democratic Republic

    Rainer Beckert

  3. Sektion Chemie, Technische Universität Dresden, DDR-8027, Dresden, German Democratic Republic

    Jürgen Fabian

Authors
  1. Vilmos Fülöp
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  2. Alajos Kalman
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  3. Rainer Beckert
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  4. Jürgen Fabian
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Fülöp, V., Kalman, A., Beckert, R. et al. On the reaction of dithiocarbamates with nitrogen-containing derivates of oxalic acid. Monatsh Chem 120, 561–569 (1989). https://doi.org/10.1007/BF00810842

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  • DOI: https://doi.org/10.1007/BF00810842

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