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Oxidative coupling of methane by carbon dioxide: a highly C2 selective La2O3/ZnO catalyst

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Abstract

In the oxidative coupling of methane by carbon dioxide, La2O3/ZnO catalysts were found to have high C2 selectivity and good stability. The coupling selectivity on La2O3/ZnO is about 90%, which is much higher than that on pure La2O3 or ZnO. The consumption ratio of carbon dioxide to methane is approximately one. X-ray diffraction analysis reveals that the structural forms of the oxides are unchanged during the reaction. The reaction mechanism for C2 formation is discussed.

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Chen, C., Xu, Y., Li, G. et al. Oxidative coupling of methane by carbon dioxide: a highly C2 selective La2O3/ZnO catalyst. Catal Lett 42, 149–153 (1996). https://doi.org/10.1007/BF00810680

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  • DOI: https://doi.org/10.1007/BF00810680

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