Abstract
A statistical analysis based on crystal structure results of 4-coordinated complexes of Ni, Pd, and Pt containing triphenylphosphine as ligand has been performed using the Cambridge Structural Data Base. Distorted square-planar coordination appears as the most probable one presented by these metals.
Zusammenfassung
Es wurde unter Verwendung der Cambridge Strukturdatenbank eine statistische Analyse von Resultaten an vier-koordinierten Komplexen des Ni, Pd und Pt mit Triphenylphosphin-Ligand durchgeführt. Dabei ergab sich eine verzerrte quadratisch-planare Koordination als die am meisten wahrscheinliche Geometrie.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Allen F. H., Kennard O., Taylor R. (1983) Acc. Chem. Res.16:146
Snedecor G. W., Cochran W. G. (1980) The comparison of two samples. 7th Edn., Statistical Methods. Iowa State University Press, Ames, Iowa, p. 83
Orpen A. G., Brammer L., Allen F. H., Kennard O., Watson D. G., Taylor R. (1989) J. Chem. Soc. Dalton Trans.: S1
Allen F. H., Kennard O., Watson D. G., Brammer L., Orpen A. G., Taylor R. (1987) J. Chem. Soc. Perkin Trans. II: S1
Hartley F. R. (1973) Chem. Soc. Rev.2: 163
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Llamas-Saiz, A.L., Foces-Foces, C. Geometrical characteristics of four-coordinate complexes of Ni, Pd, and Pt containing triphenylphosphine as ligand. Monatsh Chem 124, 243–248 (1993). https://doi.org/10.1007/BF00810579
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF00810579