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Chemie polyfunktioneller Moleküle, 94 Chrom- und Wolfram-pentacarbonylderivate des 4-Methyl-1,2,6-triphosphatricyclo[2.2.1.02,6]heptans (P3-Nortricyclans)

Chemistry of polyfunctional molecules, 94. Chromium- and tungsten-pentacarbonyl derivatives of 4-methyl-1,2,6-triphosphatricyclo[2.2.1.02,6]heptane (P3-nortricyclane)

  • Anorganische Und Physikalische Chemie
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Abstract

The P3-nortricyclane 4-methyl-1,2,6-triphosphatricyclo[2.2.1.02,6]heptane, CH3C(CH2P)3, (1), is synthesized in a better yield than earlier described from P4, a Na/K alloy, and CH3C(CH2Br)3 in boiling 1,2-dimethoxyethane. It reacts withM(CO)5 thf (M=Cr, W) in the molar ratios of 1:1, 1:2, and 1:3 to form the pentacarbonylmetal complexes CH3C(CH2P)3[M(CO)5] n [n=1, 2, 3;M=Cr (a), W (b)], (2 a, b–4 a, b).1 gives with Mo(CO)5 thf only mixtures of CH3C(CH2P)3[Mo(CO)5] n andcis-Mo(CO)4 derivatives, which were identified by their infrared active A1 v(CO) modes at 2075 and 2025 cm−1.

All the new compounds have been characterized also by their1H{31P},31P{1H} NMR, IR,Raman, and mass spectra.

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  1. Institut für Anorganische Chemie, Universität Erlangen-Nürnberg, D-8520, Erlangen, Germany

    Jochen Ellermann & Alfons A. M. Demuth

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  1. Jochen Ellermann
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  2. Alfons A. M. Demuth
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Ellermann, J., Demuth, A.A.M. Chemie polyfunktioneller Moleküle, 94 Chrom- und Wolfram-pentacarbonylderivate des 4-Methyl-1,2,6-triphosphatricyclo[2.2.1.02,6]heptans (P3-Nortricyclans). Monatsh Chem 118, 183–196 (1987). https://doi.org/10.1007/BF00810051

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  • DOI: https://doi.org/10.1007/BF00810051

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