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Verfeinerung der Kristallstruktur des Dicaesium-Tetraazido-Zinkates Cs2Zn(N3)4 und die Kristallstrukturen komplexer Zinkazide

Crystal structure refinement of Cs2Zn(N3)4 and the crystal structures of complex zinc azides

  • Anorganische Und Physikalische Chemie
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Summary

The crystal structure of dicesium-tetraazido-zincate, Cs2Zn(N3)4, has been refined from single crystal X-ray-diffractometer data. The previously reported orthorhombic structure, consisting of isolated Zn(N3)4-tetrahedra was confirmed and improved lattice parameters and atomic distances were determined. The azide groups are asymmetric and the coordination of central nitrogen atoms to cesium was observed. A table of structure data and mean atomic distances for fourteen zinc-azide compounds is added and the structures are discussed.

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Authors and Affiliations

  1. Institut für Physikalische und Theoretische Chemie, Technische Universität Graz, A-8010, Graz, Austria

    Franz A. Mautner & Harald Krischner

  2. Laboratoire de Cristallographie, Université de Geneve, CH-1211, Geneva, Switzerland

    Franz A. Mautner

Authors
  1. Franz A. Mautner
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  2. Harald Krischner
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Herrn Prof. Dr. Karl Torkar zum 70. Geburtstag gewidmet

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Mautner, F.A., Krischner, H. Verfeinerung der Kristallstruktur des Dicaesium-Tetraazido-Zinkates Cs2Zn(N3)4 und die Kristallstrukturen komplexer Zinkazide. Monatsh Chem 121, 91–97 (1990). https://doi.org/10.1007/BF00809520

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  • DOI: https://doi.org/10.1007/BF00809520

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