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Alkyl- und Arylsulfensäureanilide durch Cycloeliminierung von Alkenen aus Sulfimiden, 2. Thermolyse von 3-Alkylthiopropannitril-bzw. 3-Alkylthiopropansäuremethylester-S-(N-aryl)-imiden

Alkyl- and arylsulfenanilides by cycloelimination of alkenes from sulfimides, 2. Thermolysis of 3-alkylthio-propionitrile- or methyl 3-alkylthio-propanoate S-(N-aryl)imides

  • Organische Chemie Und Biochemie
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Summary

A series of alkyl- and arylsulfenanilides has been prepared by thermal cycloelimination of acrylonitrile or methyl acrylate from N-aryl sulfimides derived from 3-alkylthio-propionitriles or methyl 3-alkylthio-propanoates. Compared to reactions in earlier studies [1] cycloelimination proceeds much faster at very mild conditions, thus allowing a one-pot synthesis of sulfenanilides from corresponding 3-alkyl-thio-propionitriles or 3-alkylthio-propanoates.

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Authors and Affiliations

  1. Institut für Organische Chemie, Universität Wien, A-1090, Wien, Österreich

    Walter Franek & Peter K. Claus

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  1. Walter Franek
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  2. Peter K. Claus
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Franek, W., Claus, P.K. Alkyl- und Arylsulfensäureanilide durch Cycloeliminierung von Alkenen aus Sulfimiden, 2. Thermolyse von 3-Alkylthiopropannitril-bzw. 3-Alkylthiopropansäuremethylester-S-(N-aryl)-imiden. Monatsh Chem 121, 385–392 (1990). https://doi.org/10.1007/BF00809455

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  • DOI: https://doi.org/10.1007/BF00809455

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