Konzentrationen von Isomeren des Typs P _m As_4−m X ₃ in P₄S₃-As₄S₃- und P₄Se₃-As₄Se₃-Mischungen

Abstract

The reactions of P₄S₃ with As₄S₃ and of P₄Se₃ with As₄Se₃ in the molten state yields molecules of the type P _m As_4−m S₃ and P _m As_4−m Se₃, respectively. A method was developed to separate the different components by the HPLC technique, and to determine their concentrations. The identification of the isomers in the HPLC pattern was achieved with the aid of the LC-MS method. In the selenium system, the distribution of the different species is statistical. In the system P₄S₃-As₄S₃, the formation of PAs₃S₃ with one phosphorus atom in the apical position is favoured.