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Phase diagram of the selenium–sulfur system in the pressure range 1 × 10–5–1 × 10–1 MPa

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Abstract

The partial pressures of the components in the saturated vapor of the Se–S system were determined and presented as the temperature–concentration dependences. Based on these data, the boundaries of the melt–vapor phase transition at atmospheric pressure and in vacuum (1350, 100, and 10 Pa) were calculated. A complete phase diagram was constructed, which included the vapor–liquid equilibrium fields at atmospheric and low pressures, whose boundaries allowed us to determine the behavior of sulfur and selenium during distillation separation.

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Authors and Affiliations

  1. Earth Sciences, Metallurgy, and Enrichment Center, Almaty, Kazakhstan

    V. N. Volodin, N. M. Burabaeva, S. A. Trebukhov & A. A. Ersaiynova

Authors
  1. V. N. Volodin
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  2. N. M. Burabaeva
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  3. S. A. Trebukhov
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  4. A. A. Ersaiynova
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Corresponding author

Correspondence to N. M. Burabaeva.

Additional information

Original Russian Text © V.N. Volodin, N.M. Burabaeva, S.A. Trebukhov, A.A. Ersaiynova, 2016, published in Zhurnal Fizicheskoi Khimii, 2016, Vol. 90, No. 11, pp. 1663–1668.

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Volodin, V.N., Burabaeva, N.M., Trebukhov, S.A. et al. Phase diagram of the selenium–sulfur system in the pressure range 1 × 10–5–1 × 10–1 MPa. Russ. J. Phys. Chem. 90, 2183–2187 (2016). https://doi.org/10.1134/S0036024416110303

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  • DOI: https://doi.org/10.1134/S0036024416110303

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