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Lanthanide perchlorate complexes of 4-nitroquinoline-1-oxide and 5-nitroisoquinoline-2-oxide

Lanthanid-Perchlorat-Komplexe von 4-Nitrochinolin-1-oxid und 5-Nitroisochinolin-2-oxid

  • Anorganische Und Physikalische Chemie
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Abstract

Novel complexes of lanthanide perchlorates with 4-nitroquinoline-1-oxide (NQNO) and 5-nitroisoquinoline-2-oxide (NIQNO) have been prepared and characterized. The complexes have the general formulaeLn(NQNO)8(ClO4)3 (whereLn=La-Nd), Ln(NQNO)7(ClO4)3 (whereLn=Gd-Yb),Ln(NIQNO)9(ClO4)3 (whereLn=La-Nd), andLn(NIQNO)7(ClO4)3 (whereLn=Gd-Yb). The IR, proton NMR spectral data indicate the coordination of the N—O group of the ligands to he lanthanide ions.

Abstract

de|Es wurden neue Komplexe von Lanthanidperchloraten mit 4-Nitrochinolin-1-oxid (NQNO) und 5-Nitroisochinolin-2-oxid (NIQNO) dargestellt und charakterisiert. Die Komplexe haben die allgemeinen FormelnLn(NQNO)8(ClO4)3 (mitLn=La-Nd),Ln(NQNO)7(ClO4)3 (mitLn=Gd-Yb),Ln(NIQNO)9(ClO4)3 (mitLn=La-Nd) undLn(NIQNO)7(ClO4)3 (mitLn=Gd-Yb). Die IR- und NMR-Daten zeigen die Koordination der N—O-Gruppe der Liganden zum Lanthanidenion an.

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References

  1. Kalyanasundaram R.,Navaneetham N. S.,Soundararajan S., Proc. Ind. Acad. Sci., in press.

  2. Katritzky A. R.,Randall E. W.,Sutton L. E., J. Chem. Soc.1957, 1769.

  3. Ochiai E., J. Org. Chem.18, 534 (1953).

    Google Scholar 

  4. Ochiai E.,Ishikawa M., J. Pharm. Soc. Japan65 4 A (1945); C.A.45, 8527 (1951).

  5. Lyle S. S., Rahman M. M., Talanta10, 1177 (1963).

    Google Scholar 

  6. Welcher F. J., Organic Analytical Reagents. New York: Van Nostrand. 1947.

    Google Scholar 

  7. Willard H. H., Merrit L. L., Dean J. A., Instrumental Methods of Analysis, 4th ed., p. 89. New Delhi: Affiliated East West.

  8. Geary W. J., Coord. Chem. Rev.7, 81 (1971).

    Google Scholar 

  9. Nelson J. H., Nathan L. C., Ragsdale R. O., Inorg. Chem.7, 1840 (1968).

    Google Scholar 

  10. Kawazie Yutaka, Chem. Pharm. Bull.13, 396 (1965).

    Google Scholar 

  11. Armarego W. L. F.,Batterharn T. J., J. Chem. Soc. (B)1966, 750.

  12. Sinha S. P., Spectrochmica Acta22, 57 (1966).

    Google Scholar 

  13. Sinha S. P., J. Inorg. Nucl. Chem.33, 2205 (1971).

    Google Scholar 

  14. Karraker D. G., Inorg. Chem.7, 473 (1968).

    Google Scholar 

  15. Jagannathan R., Soundararajan S., J. Coord. Chem.9, 31 (1979).

    Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Indian Institute of Science, 560 012, Bangalore, India

    R. Kalyanasundaram, N. S. Navaneetham & S. Soundararajan

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  1. R. Kalyanasundaram
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  2. N. S. Navaneetham
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  3. S. Soundararajan
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Kalyanasundaram, R., Navaneetham, N.S. & Soundararajan, S. Lanthanide perchlorate complexes of 4-nitroquinoline-1-oxide and 5-nitroisoquinoline-2-oxide. Monatsh Chem 116, 913–919 (1985). https://doi.org/10.1007/BF00809184

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  • DOI: https://doi.org/10.1007/BF00809184

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