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Über Reaktionen mit Betain, 15. Mitt. Darstellung von stabilen Yliden aus Betain

Reactions with betaine, XV. Synthesis of stable ylides from betaine

  • Organische Chemie Und Biochemie
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Monatshefte für Chemie / Chemical Monthly Aims and scope Submit manuscript

Abstract

Trimethylammonium-di-trifluoroacetyl-methylide (1) was hydrolysed in both aqueous-acidic and basic milieu to form the corresponding salts2 and4a of trimethylammonium-trifluoroacetyl-methylid by loss of a trifluoroacetyl group.1 in contrast does not form salts with alkylhalides or water-free acids. Treatment of the hydroiodide4a with silver oxide in aqueous solution affords the very stable, salt-free trimethylammonium-trifluoroacetylmethylid (8).

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Literatur

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Authors and Affiliations

  1. Institut für Organische Chemie, Karl-Franzens-Universität Graz, A-8010, Graz, Österreich

    Helga Wittmann & Erich Ziegler

Authors
  1. Helga Wittmann
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  2. Erich Ziegler
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Additional information

Herrn Dir. Dr.Guido Schetty-Müller, Aesch, Schweiz, zur Vollendung des 70. Lebensjahres gewidmet.

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Wittmann, H., Ziegler, E. Über Reaktionen mit Betain, 15. Mitt. Darstellung von stabilen Yliden aus Betain. Monatsh Chem 113, 1451–1458 (1982). https://doi.org/10.1007/BF00808944

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  • DOI: https://doi.org/10.1007/BF00808944

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