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Synthesis of 3-(aminomethyl)-pyridylpentaphenoxycyclotriphosphazene and its complex formation with copper(II) nitrate. Molecular structure of {Cu[N3P3(OC6H5)5(NHCH2-(3-C5H4N))]2(NO3)2}

Synthese von 3-(Aminomethyl)pyridylpentaphenoxycyclotriphosphazen und seine Komplexibildung mit Kupfer(II)nitrat. Molekülstruktur von {Cu[N3P3(OC6H5)5(NHCH2(3-C5H4N))]2(NO3)2}

  • Anorganische Und Physikalische Chemie
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Summary

The reaction of monochloropentaphenoxycyclotriphosphazene with 3-(aminomethyl)pyridine yields 3-(aminomethyl)pyridylpentaphenoxycyclotriphosphazene (1), a new N-donor ligand with five nitrogen atoms as potential coordination centers. Complex formation with copper(II) nitrate yields compound2 with the general structure Cu(1)2(NO3)2. The X-ray structure analysis shows that the copper ion is coordinated by two nitrogen atoms of the pyridine rings and four oxygen atoms of the unsymmetrical bidentate nitrate groups in aJahn-Teller distorted octahedral arrangement.

Zusammenfassung

Die Reaktion von Monochlorpentaphenoxycyclotriphosphazen mit 3-(Aminomethyl)pyridin ergibt 3-(Aminomethyl)pyridylpentaphenoxycyclotriphosphazen (1), einen neuen N-Donor Liganden mit fünf Strickstoffatomen als potentielle Metallkoordinationszentren. Bei der Umsetzung von1 mit Kupfer(II)nitrat entsteht der Metallkomplex2 mit der Zusammensetzung Cu(1)2(NO3)2. Die durch Röntgenstrukturanalyse ermittelte Molekülstruktur zeigt, daß das Kupferion von zwei Stickstoffatomen der Pyridinringe sowie vier Sauerstoffatomen der unsymmetrisch zweizähnigen NitratgruppenJahn-Teller-verzerrt oktaedrisch umgeben ist.

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References

  1. Audrieth LF, Steinmann R, Toy ADF (1943) Chem Rev32: 109

    Google Scholar 

  2. Migachev GI, Stepanov BI (1966) Russ J Inorg Chem (Engl Transl)11: 929

    Google Scholar 

  3. Allcock HR, Levin LL, Austin PE (1986) Inorg Chem25: 2281

    Google Scholar 

  4. Bertani R, Facchin G, Gleria M (1989) Inorg Chim Acta165: 73

    Google Scholar 

  5. Carriedo GA, Elipe PG, Alonso FJG, Fernández-Catuxo L, Diaz MR, Granda SG (1995)498: 207

  6. Diefenbach U, Allcock HR (1994) Inorg Chem33: 4562

    Google Scholar 

  7. Diefenbach U, Kretschmann M, Çavdarci Ö (1994) Phosphorus Sulfur93–94: 415

    Google Scholar 

  8. Diefenbach U, Kretschmann M (1995) Phosphorus Sulfur (in press)

  9. Andrews HP, Ozin GA (1989) Chem Mater1: 474

    Google Scholar 

  10. Sheats JE, Carraher CE Jr Pittman CU Jr (eds) (1985) Metal-Containing polymeric systems. Plenum, New York

    Google Scholar 

  11. Lyons AM, Pearce EM, Vasile MJ, Mujsce AM, Waszcak JV (1988) In: Zeldin M, Wynne KJ, Allcock HR (eds) Inorganic and organometallic polymers. ACS Symposium Series, vol. 360. American Chemical Society, Washington DC

    Google Scholar 

  12. Allcock HR, Desorcie JL, Riding GH (1987) Polyhedron6: 119

    Google Scholar 

  13. Gallicano KD, Paddock NL, Rettig SJ, Trotter J (1979) Inorg Nucl Chem Lett15: 417

    Google Scholar 

  14. Chandrasekaran A, Krishnamurthy SS, Nethaji M (1993) Inorg Chem32: 6102

    Google Scholar 

  15. Justin Thomas KR, Chandrasekhar V, Pal P, Scott SR, Hallford R, Cordes AW (1993) Inorg Chem32: 606

    Google Scholar 

  16. Allcock HR, Greigger PP, Gardner JE, Schmutz JL (1979) J Am Chem Soc101: 606

    Google Scholar 

  17. Allcock HR, Neenan TX, Boso B (1985) Inorg Chem24: 2656

    Google Scholar 

  18. Trotter J, Whitlow SH (1970) J Chem SocA: 455

    Google Scholar 

  19. Allcock HR, Allen RW, O'Brian JP (1977) J Am Chem Soc99: 3984

    Google Scholar 

  20. Allen RW, O'Brian JP, Allcock HR (1977) J Am Chem Soc99: 3987

    Google Scholar 

  21. Schmidtpeter A, Blanck K, Ahmed FR (1976) Angew Chem Int Ed Engl15: 488

    Google Scholar 

  22. Chandrasekaran A, Nethaji M (1992) Phosphorus Sulfur64: 99

    Google Scholar 

  23. Addison CC, Logan N, Wallwork SC, Garner CD (1971) Q Rev25: 289

    Google Scholar 

  24. Diefenbach U, Kretschmann M, Chem Ber (submitted)

  25. Allcock HR, Kugel RL (1965) J Am Chem Soc87: 4216

    Google Scholar 

  26. McBee ET, Okuhara K, Morton CJ (1966) Inorg Chem5: 450

    Google Scholar 

  27. Sheldrick GM (1986) SHELXS-86, Göttingen

  28. Sheldrick GM (1993) SHELXL-93 Program for crystal structure determination, Göttingen

Download references

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Authors and Affiliations

  1. Institut für Anorganische und Analytische Chemie der Freien Universität Berlin, D-14195, Berlin, Germany

    U. Diefenbach, M. Kretschmann & Ö. Çavdarci

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  1. U. Diefenbach
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  2. M. Kretschmann
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  3. Ö. Çavdarci
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Diefenbach, U., Kretschmann, M. & Çavdarci, Ö. Synthesis of 3-(aminomethyl)-pyridylpentaphenoxycyclotriphosphazene and its complex formation with copper(II) nitrate. Molecular structure of {Cu[N3P3(OC6H5)5(NHCH2-(3-C5H4N))]2(NO3)2}. Monatsh Chem 127, 989–996 (1996). https://doi.org/10.1007/BF00807569

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  • DOI: https://doi.org/10.1007/BF00807569

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