Summary
An electrochemical study on N,N′-Propylene-bis-(salicylideneiminato) Mn(III) was performed using cyclic voltammetry with convolution-deconvolution and digital simulation in phosphate buffer solutions ofpH values ranging from 5–9.5 at a hanging mercury drop electrode (HMDE). The reduction pathway of the investigated complex shows that a moderately fast transfer of one electron is followed by a very fast chemical reaction (E q C irr scheme). The electrochemical parameters have been determined experimentally andvia digital simulation experiments.
Zusammenfassung
N,N′-Propylen-bis-(salicylideniminato)-Mn(III) wurde in Phosphatpufferlösungen mitpH-Werten im Bereich von 5–9.5 an einer Quecksilbertrofelektrode (HMDE) mittels cyclischer Voltammetrie (Konvolution-Dekonvolution, digitale Simulation) elektrochemisch untersucht. Ein mäßig schneller Transfer eines Elektrons wird von einer sehr schnellen chemischen Reaktion gefolgt (E q C irr-Schema). Die elektrochemischen Parameter wurden experimentell und durch Simulations-experimente bestimmt.
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El-Hallag, I.S., Ghoneim, M.M. Electrochemical investigation of N,N′-Propylene-bis-(salicylideneiminato) Mn(III) in phosphate buffer solutions. Monatsh Chem 127, 487–494 (1996). https://doi.org/10.1007/BF00807073
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DOI: https://doi.org/10.1007/BF00807073