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Fluordiazadiphosphetidine, 14. Mitt.: Nucleophile Substitutionsreaktionen von 1-Chlormethyl-2,2,2,4,4,4-hexafluor-3-methyl-1,3,2λ5,4λ5-diazadiphosphetidin und 1,3-Bis(chlormethyl)-2,2,2,4,4,4-hexafluor-1,3,2λ5,4λ5-diazadiphosphetidin mit ausgewählten metallorganischen Reagentien

Fluorodiazadiphosphetidines, 14: Nucleophilic substitution reactions of 1-chloromethyl-2,2,2,4,4,4-hexafluoro-3-methyl-1,3,2λ5,4λ5-diazadiphosphetidine and 1,3-bis-(chloromethyl)-2,2,2,4,4,4-hexafluoro-1,3,2λ5,4λ5-diazadiphosphetidine with selected organometallic reagents

  • Anorganische Und Physikalische Chemie
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Abstract

Photochemical chlorination of (CH3NPF3)2 yields ClCH2(NPF3)2CH3(I) and ClCH2(NPF3)2CH2Cl (II). By reaction with organometallics unsymmetric N-substituted hexafluorodiazadiphosphetidines are synthesized. Depending on the nucleophilic strength of the used organometallic the chlorine atom of the N-CH2Cl group can be selectively substituted versus an organic substituent without side-reaction at the phosphorus atom.

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Literatur

  1. Meindl W., Utvary K., Monatsh. Chem.110, 135 (1978).

    Google Scholar 

  2. Houben-Weyl, Band 13/2 a Metallogran. Verbindungen, Be Mg Ca Sr Ba Zn Cd. Stuttgart: G. Thieme. 1973.

    Google Scholar 

  3. Nelson J., Iowa Coll J.12, 145 (1937).

    Google Scholar 

  4. Schlak O., Dissertation, Techn. Universität Braunschweig, 1974.

  5. Drach B., Zhmurova I., Zh. Obshch. Khim.37, 892 (1967).

    Google Scholar 

  6. Hahn H., unveröffentlichte Ergebnisse.

  7. Whitmore F. C., Badertscher D. E., J. Amer. Chem. Soc.55, 1559 (1933).

    Google Scholar 

  8. Gilman H.,Catlin W. E., Organic Synthesis, Coll. Vol. I, 188.

  9. Allen C. F. H.,Converse S., Organic Synthesis, Coll. Vol. I, 2. Aufl., S. 226.

  10. Hiers G. H., Organic Synthesis, Coll. Vol. I, 2. Aufl., S. 550.

  11. Ziegler K., Tiemann P., Ber.55, 3414 (1922).

    Google Scholar 

  12. Staab A., Binnings F., Ber.100, 293 (1967).

    Google Scholar 

  13. Kusama F., Koive D., J. Chem. Soc. Japan72, 871 (1951).

    Google Scholar 

  14. US-Pat. 2855397 (1955), Metal & Thermit Corp., Erf.:Ramsden H. E., C.A.54, 22682 (1960).

  15. Holtkamp H., Blomberg L., Bickelhaupt F., J. Organomet. Chem.19, 279 (1969).

    Google Scholar 

  16. Nützel K., Methoden der organischen Chemie,Houben-Weyl, Bd. XIII, 2a, S. 592 ff. Stuttgart: G. Thieme. 1973.

    Google Scholar 

  17. Bürger H., Sawodny W., Wannagat U., J. Organomet. Chem.3, 113 (1965).

    Google Scholar 

  18. Harris R., Woodman C., Mol. Phys.10, 437 (1966).

    Google Scholar 

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Authors and Affiliations

  1. Institut für Anorganische Chemie, Technische Universität Wien, A-1060, Wien, Österreich

    Heinrich Hahn, Wolfgang Meindl & Kurt Utvary

Authors
  1. Heinrich Hahn
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  2. Wolfgang Meindl
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  3. Kurt Utvary
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Hahn, H., Meindl, W. & Utvary, K. Fluordiazadiphosphetidine, 14. Mitt.: Nucleophile Substitutionsreaktionen von 1-Chlormethyl-2,2,2,4,4,4-hexafluor-3-methyl-1,3,2λ5,4λ5-diazadiphosphetidin und 1,3-Bis(chlormethyl)-2,2,2,4,4,4-hexafluor-1,3,2λ5,4λ5-diazadiphosphetidin mit ausgewählten metallorganischen Reagentien. Monatsh Chem 116, 157–166 (1985). https://doi.org/10.1007/BF00798451

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  • DOI: https://doi.org/10.1007/BF00798451

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