Abstract
The composition and stability constants of Tl(I) complexes with dithiodipropionic acid have been studied employingLingane's polarographic method,Calvin-Melchior'spH-metric technique, and conductance measurements. The thermodynamic functions ΔG, ΔH and ΔS involved in complex formation are also determined at 30°C.
Zusammenfassung
Die Zusammensetzung und die Stabilitätskonstanten von Tl(I)-Komplexen mit Dithiodipropionsäure wurde mittels polarographischer Methoden (nachLingane),pH-metrischer Titration (nachCalvin-Melchior) und Leitfähigkeitsmessungen untersucht. Die thermodynamischen Funktionen der Komplexbildung (ΔG, ΔH und ΔS) wurden bei 30°C bestimmt.
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Saxena, R.S., Gupta, A. Electrochemical studies on the composition, stability constants and thermodynamics of TI(I) complexes with dithiodipropionic acid. Monatsh Chem 115, 1293–1298 (1984). https://doi.org/10.1007/BF00798306
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DOI: https://doi.org/10.1007/BF00798306