Conclusions
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1.
Ta in MoSe2 acts as an acceptor impurity, and alloying with it sharply increases the electrical conductivity of the compound.
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2.
At x=0.12 · 10−2, the compound Mo1−xTaxSe2 is a nondegenerate semiconductor; compounds with x≥ 0.56 · 10−2 must be classed as semimetals.
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3.
The effective masses of charge carriers in Mo1−xTaxSe2 alloys are close to m0. This indicates that holes generated as a result of alloying with tantalum are located in the valency zone (Fig. 1b).
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Literature cited
L. N. Brixner, J. Inorg. Nucl. Chem.,24, 257 (1964).
D. Boes, I. E. E. E. Trans.,2, 457 (1964).
W. T. Hicks, J. Electrochem. Soc.,111, 1058 (1964).
I. A. Wilson and A. D. Voffe, Advan. Phys.,18, 194 (1969).
R. Huisman, R. de Jonge, et al., Solid State Chem.,3, 56 (1971).
V. L. Kalikhman, A. N. Zelikman, et al., Izv. Akad. Nauk SSSR, Neorgan. Mat.,7, No. 7 (1971).
R. Fivaz and E. Mooser, Phys. Rev.,163, 743 (1967).
V. I. Fistul', Strongly Doped Semiconductors [in Russian], Nauka, Moscow (1967), p. 141.
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Translated from Poroshkovaya Metallurgiya, No. 11 (131), pp. 75–79, November, 1973.
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Kalikhman, V.L., Kasiyan, I.M. & Mikhailyuk, I.P. Mechanism of the electrical conductivity of quasibinary MoSe2-TaSe2 (Mo1−xTaxSe2) alloys. Powder Metall Met Ceram 12, 922–925 (1973). https://doi.org/10.1007/BF00794632
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DOI: https://doi.org/10.1007/BF00794632