Abstract
At 4.0 MPa, CO2 hydrogenation over a RhNA-Y catalyst yields only saturated and essentially linear hydrocarbons (up to C7). In contrast, CO hydrogenation gives a more complex mixture including olefins (α and β), paraffins (linear and branched) and oxygenates. Addition of 1-butene provides a plausible interpretation of these differences.
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G. van der Lee, A.G.T.M. Bastein, J. van den Boogert, B. Schuller, H.Y. Luo and V. Ponec, J. Chem. Soc., Faraday Trans. 1 83 (1987) 2103;
H.Y. Luo, A.G.T.M. Bastein, A.A.J.P. Mulder and V. Ponec, Appl. Catal. 38 (1988) 241;
F.G.A. van den Berg, J.H.E. Glezer and W.M.H. Sachtler, J. Catal. 93 (1985) 340.
Several papers in:Proc. IX Int. Congress on Catalysis, eds. M.J. Phillips and M. Ternan, Vol. 2 (The Chemical Institute of Canada, Ottawa, 1988).
F. Lefebvre, P. Gelin, C. Naccache and Y. Ben Taarit, in:Proc. Sixth Int. Zeolite Conf., eds. D. Olson and A. Bisio (Butterworth, London, 1984) p. 435.
W.R. Hastings, C.J. Cameron, M.J. Thomas and M.C. Baird, Inorg. Chem. 27 (1988) 3024.
I. Wender and A. Sayari,Chemistry and Uses of Carbon Dioxide (EPRI, Palo Alto, 1986) Project 2563-5, AP-4631.
R.T. Hanlon and C.N. Satterfield, Energy & Fuels 2 (1988) 196 and references therein.
D.S. Jordan and A.T. Bell, J. Phys. Chem. 90 (1986) 4797 and references therein.
A. Sayari, J.R. Morton and K.F. Preston, J. Phys. Chem. 91 (1987) 899.
A. Sayari, J.R. Morton and K.F. Preston, J. Chem. Soc., Faraday Trans. 1 84 (1988) 413.
L. Tebassi, A. Sayari, A. Ghorbel, M. Dufaux, Y. Ben Taarit and C. Naccache, in:Proc. Sixth Int. Zeolite Conf., eds. D. Olson and A. Bisio (Butterworth, London, 1984) p. 368.
G. Bergeret, P. Gallezot, P. Gelin, Y. Ben Taarit, F. Lefebvre, C. Naccache and R.D. Shannon, J. Catal. 104 (1987) 279.
G.C. Bond and D.G. Richards, Appl. Catal. 28 (1986) 303.
Ref. [2], Several papers in: p. 674.
S.M. Davies and G.A. Somorjai, in:The Chemical Physics of Solid Surfaces and Heterogeneous Catalysis, eds. D.A. King and D.P. Woodruff, Vol. 4 (Elsevier, Amsterdam, 1984) Ch. 7 and references therein.
R. Oukaci, A. Sayari and J.G. Goodwin, Jr., J. Catal. 102 (1986) 126.
R. Oukaci, J.C.S. Wu and J.G. Goodwin, Jr., J. Catal. 107 (1987) 471; J. Catal. 110 (1988) 47.
W.M.H. Sachtler, Faraday Discuss. 72 (1981) 7.
J.W.A. Sachtler and G.A. Somorjai, J. Catal. 81 (1983) 77.
V. Ponec, Catal. Rev. Sci. Eng. 11 (1975) 41; Adv. Catal. 32 (1983) 149.
L. Tebassi, A. Sayari, A. Ghorbel, M. Dufaux and C. Naccache, J. Mol. Catal. 25 (1984) 397.
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Sayari, A. Carbon oxides hydrogenation on RhNa-Y: Addition of 1-butene. Catal Lett 2, 173–179 (1989). https://doi.org/10.1007/BF00775067
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DOI: https://doi.org/10.1007/BF00775067