Abstract
In the hydrogenation of carbon monoxide, alkali cations were found to be effective as modifiers for highly dispersed cobalt catalyst to improve the selectivities of C2-oxygenated compounds, especially acetic acid and acetaldehyde, and to increase the olefin/paraffin ratio of hydrocarbons. These effects are ascribed to depression of the hydrogenating ability of the catalyst by modification with alkali cations.
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References
S.J. Tomson, J. Chem. Soc., Faraday Trans, 1, 83 (1987) 1893.
D.W. Dweyer, in:Materials Science Monograph 57. Physics and Chemistry of Alkali Metal Adsorption, eds. H.P. Bonzel, A.M. Bradshaw and G. Ertl (Elsevier, Amsterdam, 1989) p. 307.
K. Takeuchi, M. Matsuzaki, T. Hanaoka, H. Arakawa, Y. Sugi and K. Wei, J. Mol. Catal. 55 (1989) 61.
K. Takeuchi, T. Matsuzaki, H. Arakawa and Y. Sugi, Appl. Catal. 18 (1985) 325.
K. Takeuchi, T. Matsuzaki, H. Arakawa, T. Hanaoka and Y. Sugi, Appl. Catal. 48 (1989) 149.
T. Matsuzaki, K. Takeuchi, H. Arakawa, T. Hanaoka and Y. Sugi, in:Catalytic Science and Technology, Vol. 1, eds. S. Yoshida, N. Takezawa and T. Ono (Kodansha, Tokyo, Japan and VCH, Weinheim, Germany, 1991) p. 249.
V.L. Kuznetsov, A.S. Lisitsyn, A.V. Golovin, M.N. Aleksandrov and Yu.I. Yermakov, in:Homogeneous and Heterogeneous Catalysis, eds. Yu.I Yermakov and V. Likholobov (VNU Science Press, Utrecht, The Netherlands 1986) p. 1065.
A.S. Lisityn, A.V. Golovin, A.L. Chuvilin, V.L. Kuznetsov A.V. Romanenko, A.F. Danilyuk and Yu.I. Yermakov, Appl. Catal. 55 (1989) 235.
Y. Kuwahara, H. Hamada, Y. Kintaichi, T. Ito and K. Wakabayashi, Chem. Lett. 205 (1985).
Y. Kikuzono, S. Kagami, S. Naito, T. Onishi and K. Tamaru, Faraday Discuss., Chem. Soc. 72 (1981) 135.
C. Diange, H. Idriss, J.P. Hindermann and A. Kienemann, Appl. Catal. 51 (1989) 165.
M. Inoue, T. Miyake, Y. Takegami and T. Inui, Appl. Catal. 11 (1984) 103.
K. Fujimoto and T. Oba, Appl. Catal. 13 (1985) 289.
H. Arakawa, T. Hanaoka, K. Takeuchi, T. Matsuzaki and Y. Sugi,Proc. 9th Int. Congr. Catal., Calgary, Canada, 1988, p. 602.
S.C. Chuang, J.G. Goodwin and I. Wender, J. Catal. 95 (1985) 435.
H. Arakawa and A.T. Bell, Ind. Eng. Chem., Process Des. Dev. 22 (1983) 97.
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Matsuzaki, T., Hanaoka, T.a., Takeuchi, K. et al. Effects of modification of highly dispersed cobalt catalysts with alkali cations on the hydrogenation of carbon monoxide. Catal Lett 10, 193–199 (1991). https://doi.org/10.1007/BF00772071
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DOI: https://doi.org/10.1007/BF00772071