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HREELS study: low-temperature reaction of NO with isolated carbon atoms adsorbed on Pt(111) surface

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Abstract

The reaction between isolated carbon atoms and nitrogen oxide molecules in the adlayer on Pt(111) surface has been studied. Carbon atoms have been deposited on the surface from the special source. The reaction was found to proceed atT ≈ 100 K and to provide, at least, two intermediate surface species, which have been assigned to adsorbed isocyanate NCOads and fulminate CNOads particles. Both intermediates dissociated into on-top state of COads and Nads under heating toT ⩽300 K.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, 630090, Novosibirsk, Russia

    M. Yu. Smirnov & V. V. Gorodetskii

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  1. M. Yu. Smirnov
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  2. V. V. Gorodetskii
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Smirnov, M.Y., Gorodetskii, V.V. HREELS study: low-temperature reaction of NO with isolated carbon atoms adsorbed on Pt(111) surface. Catal Lett 19, 233–238 (1993). https://doi.org/10.1007/BF00771759

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  • DOI: https://doi.org/10.1007/BF00771759

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