Abstract
The co-adsorption of ammonia and carbon monoxide on the Pt(111) surface was studied at temperatures <300 K using high-resolution electron energy loss spectroscopy (HREELS). The state of ammonia and carbon monoxide molecules in the co-adsorption layer was established to differ significantly from their state in individual adsorption layers. The adsorption of CO on a clean surface occurs with the primary filling of single-bound terminal sites, whereas the bridging sites are filled preferably by CO molecules in the presence of NH3,ads. The symmetry axis of ammonia molecules adsorbed on the clean surface is parallel to the normal to the surface, whereas in the co-adsorption layers the interaction with COads molecules results in the deviation of the symmetry axis toward the surface. Presumably, the observed changes in the state of adsorbed molecules are due to the donor-acceptor interaction inducing the electron density transfer from ammonia molecules across the metal surface to CO molecules.
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Kratkii spravochnik fiziko-khimicheskikh velichin [Brief Manual of Physicochemical Magnitudes], Eds K. P. Mishchenko and A. A. Ravdel, Khimiya, Leningrad, 1974, p. 144 (in Russian).
C. W. Seabury, T. N. Rhodin, R. J. Purtell, R. P. Merrill, Surf. Sci., 1980, 93, 117.
G. Fisher, Chem. Phys. Lett., 1981, 79, 452.
C. Egawa, S. Naito, K. Tamaru, Surf. Sci., 1984, 138, 279.
B. A. Sexton, G. E. Mitchell, Surf. Sci., 1980, 99, 523.
B. A. Sexton, G. E. Mitchell, Surf. Sci., 1980, 99, 539.
Y. Zhou, S. Akhter, J. M. White, Surf. Sci., 1988, 202, 357.
W. Widdra, T. Moritz, K. L. Kostov, P. König, M. Staufer, U. Birkenheuer, Surf. Sci., 1999, 430, L558.
J. E. Parmeter, Y. Wang, C. B. Mullins, W. H. Weinberg, J. Chem. Phys., 1988, 88, 5225.
J. A. Rodriguez, W. K. Kuhn, C. M. Troung, D. W. Goodman, Surf. Sci., 1992, 271, 333.
Z. Xu, L. Hanley, J. T. Yates, J. Chem. Phys., 1992, 96, 1621.
H. E. Dastoor, P. Gardner, D. A. King, Surf. Sci., 1993, 289, 279.
I. Villegas, M. J. Weaver, Surf. Sci., 1996, 367, 162.
C. Benndorf, T. E. Madey, Chem. Phys. Lett., 1983, 101, 59.
C. Klauber, M. D. Alvey, J. T. Yates, Chem. Phys. Lett., 1984, 106, 477.
M. D. Alvey, C. Klauber, J. T. Yates, J. Vac. Sci. Technol. A, 1985, 3, 1631.
D. Mocuta, J. Ahner, J. T. Yates, Surf. Sci., 1997, 383, 299.
C. Benndorf, T. E. Madey, Surf. Sci., 1983, 135, 164.
K. Jacobi, E. S. Jensen, T. N. Rhodin, R. P. Merrill, Surf. Sci., 1981, 108, 397.
O. L. C. Bracho, V. A. Ranea, I. M. Irurzun, R. Imbihl, E. E. Mola, Chem. Phys. Lett., 2011, 505, 21.
Z. Jiang, Q. Pan, M. Li, T. Yan, T. Fang, Appl. Surf. Sci., 2014, 292, 494.
Z. Jiang, P. Qin, T. Fang, Chem. Phys., 2014, 445, 59.
R. M. van Hardeveld, R. A. van Santen, J. W. Niemantsverdriet, Surf. Sci., 1996, 369, 23.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds. Parts A and B, John Wiley and Sons, New York, 1997.
F. Netzer, T. E. Madey, Surf. Sci., 1982, 119, 422.
F. Netzer, T. E. Madey, Phys. Rev. Lett., 1981, 47, 928.
M. L. Wagner, L. D. Schmidt, J. Phys. Chem., 1995, 99, 805.
P. R. Davies, M. W. Roberts, N. Shukla, D. J. Vincent, Surf. Sci., 1995, 325, 50.
T. E. Madey, C. Benndorf, Surf. Sci., 1985, 152/153, 587.
G. T. Fraser, D. D. Nelson, K. I. Peterson, W. Klemperer, J. Chem. Phys., 1986, 84, 2472.
C. H. Xia, K. A. Walker, A. R. W. McKellar, Mol. Phys. 2001, 99, 643.
H. Tochihara, G. Rocker, J. D. Redding, J. T. Yates, R. M. Martin, H. Metiu, Surf. Sci., 1986, 176, 1.
W. Erley, Surf. Sci., 1990, 240, 1.
M. J. Dresser, A.-M. Lanzillotto, M. D. Alvey, J. T. Yates, Surf. Sci., 1987, 191, 1.
A.-M. Lanzillotto, M. J. Dresser, M. D. Alvey, J. T. Yates, Surf. Sci., 1987, 191, 15.
T. Sasaki, T. Aruga, H. Kuroda, Y. Iwasawa, Surf. Sci., 1990, 240, 223.
T. Sasaki, Y. Iwasawa, Surf. Sci., 1997, 384, L798.
H. Pfnür, P. Feulner, D. Menzel, J. Chem. Phys., 1983, 79, 4613.
H. Steininger, S. Lehwald, H. Ibach, Surf. Sci., 1982, 123, 264.
V. A. Sobyanin, Poverkhnost [Surface], 1986, No. 10, 65 (in Russian).
P. R. Norton, J. W. Goodale, E. B. Selkirk, Surf. Sci., 1979, 83, 189.
J. T. Ranney, A. J. Franz, J. L. Gland, Surf. Sci., 1997, 384, L865.
H. Froitzheim, H. Hopster, H. Ibach, S. Lehwald, Appl. Phys., 1977, 13, 147.
H. Hopster, H. Ibach, Surf. Sci., 1978, 77, 109.
N. R. Avery, J. Chem. Phys., 1981, 74, 4202.
F. Bondino, G. Comelli, F. Esch, A. Locatelli, A. Baraldi, S. Lizzit, G. Paolucci, R. Rosei, Surf. Sci., 2000, 459, L467.
D. F. Ogletree, M. A. van Hove, G. A. Somorjai, Surf. Sci., 1986, 173, 351.
W. D. Mieher, L. J. Whitman, W. Ho, J. Phys. Chem., 1989, 91, 3228.
D. M. Newns, Vibrational Spectroscopy of Adsorbates, Ed. R. F. Willis, Springer-Verlag, Berlin, 1980, p. 19.
J. L. Gland, E. B. Kollin, Surf. Sci., 1981, 104, 478.
W. D. Mieher, W. Ho, Surf. Sci., 1995, 322, 151.
K. S. Krasnov, V. S. Timoshinin, T. G. Danilova, S. V. Khandozhko, Molekulyarnye postoyannye neorganicheskikh soedinenii [Molecular Constants of Inorganic Compounds], Khimiya, Leningrad, 1968, 256 pp. (in Russian).
W. K. Offermans, A. P. J. Jansen, R. A. van Santen, Surf. Sci., 2006, 600, 1714.
G. Novell-Leruth, A. Varcarcel, A. Clotet, J. M. Ricart, J. Perez-Ramirez, J. Phys. Chem. B, 2005, 109, 18061.
G. Novell-Leruth, A. Varcarcel, J. Perez-Ramirez, J. M. Ricart, J. Phys. Chem. C, 2007, 111, 860.
D. A. Daramola, G. G. Botte, Computational and Theoretical Chem., 2012, 989, 7.
A. Peronio, A. Cepellotti, S. Marchini, N. Abdurakhmanova, C. Dri, C. Africh, F. Esch, M. Peressi, G. Comelli, J. Phys. Chem. C, 2013, 117, 21186.
A. Cepellotti, A. Peronio, S. Marchini, N. Abdurakhmanova, C. Dri, C. Africh, F. Esch, G. Comelli, M. Peressi, J. Phys. Chem. C, 2013, 117, 21196.
M. Yu. Smirnov, V. V. Gorodetskii, in Mekhanizmy adsorbtsii kataliza na chistykh poverkhnostyakh metallov [Mechanisms of Catalysis and Adsorption on Clean Metal Surfaces], Ed. V. I. Savchenko, Institute of Catalysis, Sib. Otd. Akad. Nauk SSSR, Novosibirsk, 1989, p. 3 (in Russian).
P. Deshlahara, J. Conway, E. E. Wolf, W. F. Schneider, Langmuir, 2012, 28, 8408.
Y. Wang, S. de Gironcoli, N. S. Hush, J. R. Reimers, J. Am. Chem. Soc., 2007, 129, 10402.
G. Blyholder, J. Phys. Chem., 1964, 68, 2772.
A. M. Baro, H. Ibach, J. Chem. Phys., 1979, 71, 4812.
H. Ogasawara, J. Yoshinobu, M. Kawai, Surf. Sci., 1997, 386, 73.
Y. Hu, P. R. Norton, K. Griffith, J. Vac. Sci. Technol. A, 2007, 25, 645.
N. C. Yee, G. S. Chottiner, D. A. Scherson, J. Phys. Chem. B, 2005, 109, 7610.
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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2400–2407, October, 2015.
Based on the materials of the XXVI Symposium “Modern Chemical Physics” (September 20–October 1, 2014, Tuapse, Russia).
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Smirnov, M.Y. Specific features of the formation of co-adsorption layers on metal surfaces with the participation of simple molecules: NH3 + CO on Pt(111). Russ Chem Bull 64, 2400–2407 (2015). https://doi.org/10.1007/s11172-015-1169-y
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DOI: https://doi.org/10.1007/s11172-015-1169-y