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Preparation of Pd-Ag thin films by the RF-sputtering method and its catalysis for oxidative dehydrogenation of allylic alcohols

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Abstract

Pd-Ag thin films were prepared by the RF sputtering method on a Pyrex glass substrate to give monophasic alloys. Oxidation of allylic alcohols using the films gave selectively α, β-unsaturated carbonyl compounds in the presence of O2; highly dispersed Pd species on Ag, Pd7Ag93 showed 95% selectivity for acrolein from allyl alcohol at 473 K.

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Authors and Affiliations

  1. Department of Chemical Engineering, Faculty of Engineering Science, Osaka University, Toyonaka, 560, Osaka, Japan

    Masashi Yamamura, Kiyotomi Kaneda & Toshinobu Imanaka

Authors
  1. Masashi Yamamura
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  2. Kiyotomi Kaneda
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  3. Toshinobu Imanaka
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Yamamura, M., Kaneda, K. & Imanaka, T. Preparation of Pd-Ag thin films by the RF-sputtering method and its catalysis for oxidative dehydrogenation of allylic alcohols. Catal Lett 3, 203–208 (1989). https://doi.org/10.1007/BF00766394

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  • DOI: https://doi.org/10.1007/BF00766394

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