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Heterocyclic analogs of pleiadiene

XXI. Electrophilic acylation and nitration of the perimidinium cation

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The 6 position of the 1,3-dimethylperimidinium cation is readily acylated by acetic acid in polyphosphoric acid and nitrated by nitric acid in acetic acid. 6-Acetyl- and 6-nitro-1,3-dimethylperimidinium salts are converted to a mixture of 6-acetyl and 6-nitro derivatives of 1,3-dimethylperimidone and 1,3-dimethyl-2,3-dihydroperimidine on treatment with aqueous alkali.

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Literature cited

  1. I. V. Borovlev and A. F. Pozharskii, Khim. Geterotsikl. Soedin., 1688 (1975).

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  3. A. F. Pozharskii, I. V. Borovlev, and I. S. Kashparov, Khim. Geterotsikl. Soedin., 543 (1975).

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Authors and Affiliations

  1. Rostov State University, Rostov-on-Don

    I. V. Borovlev, A. F. Pozharskii & V. N. Koroleva

Authors
  1. I. V. Borovlev
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  2. A. F. Pozharskii
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  3. V. N. Koroleva
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Additional information

See [1] for communication XX.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1692–1695, December, 1975.

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Borovlev, I.V., Pozharskii, A.F. & Koroleva, V.N. Heterocyclic analogs of pleiadiene. Chem Heterocycl Compd 11, 1430–1433 (1975). https://doi.org/10.1007/BF00764544

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  • DOI: https://doi.org/10.1007/BF00764544

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