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Performance of supported Ru-Cu bimetallic catalysts prepared from nitrate precursors

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Abstract

Bimetallic Ru-Cu catalysts supported on SiO2, α-Al2O3, γ-Al2O3 have been prepared using precursors which do not contain chlorine and characterized by CO chemisorption and TPR. Catalytic activity has been tested in the propane hydrogenolysis. It has been observed that the degree of formation of bimetallic Ru-Cu aggregates depends on the support used. It is suggested that the degree of interaction between Ru and Cu is strongly influenced by the strength of the metal-support interaction.

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References

  1. M. Hansen,Constitution of Binary Alloys (McGraw-Hill, New York, 1958) p. 620.

    Google Scholar 

  2. J.H. Sinfelt, Acc. Chem. Res. 10 (1977) 15.

    Google Scholar 

  3. A.J. Rouco, G.L. Haller, J.A. Oliver and C. Kemball, J. Catal. 84 (1983) 477.

    Google Scholar 

  4. A.J. Rouco, G.L. Haller, D.E. Resasco and J. Wang, J. Catal. 84 (1983) 297.

    Google Scholar 

  5. G.C. Bond and X. Yide, J. Mol. Catal. 25 (1984) 141.

    Google Scholar 

  6. A.G. Shastri, J. Schwank and S. Galvagno, J. Catal. 100 (1986) 446.

    Google Scholar 

  7. A.J. Hong, A.J. Rouco, D.E. Resasco and G.L. Haller, J. Phys. Chem. 91 1987) 2665.

    Google Scholar 

  8. M.W. Smale and T.S. King, J. Catal. 119 (1989) 441.

    Google Scholar 

  9. D.E. Damiani, E.D. Perez Millen and A.J. Rouco, J. Catal. 101 (1986) 162.

    Google Scholar 

  10. C. Crisafulli, R. Maggiore, G. Schembari, S. Scirè and S. Galvagno, J. Mol. Catal. 50 (1989) 67.

    Google Scholar 

  11. S. Galvagno, C. Crisafulli, R. Maggiore, A. Giannetto and J. Schwank, J. Therm. Anal. 32 (1987) 471.

    Google Scholar 

  12. P. Villamil, J. Reyes, N. Rosas and R. Gomez, J. Mol. Catal. 54 (1989) 205.

    Google Scholar 

  13. C. Crisafulli, S. Galvagno, R. Maggiore, S. Scirè and L. Solarino, J. Mol. Catal. (submitted).

  14. J.H. Sinfelt, J. Catal. 29 (1973) 308.

    Google Scholar 

  15. S. Galvagno, C. Crisafulli, R. Maggiore, G.R. Tauszik and A. Giannetto, J. Therm. Anal. 30 (1985) 611.

    Google Scholar 

Download references

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Crisafulli, C., Galvagno, S., Maggiore, R. et al. Performance of supported Ru-Cu bimetallic catalysts prepared from nitrate precursors. Catal Lett 6, 77–83 (1990). https://doi.org/10.1007/BF00764055

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  • DOI: https://doi.org/10.1007/BF00764055

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