Skip to main content
Log in

Low temperature heat release, sound velocity and attenuation, specific heat and thermal conductivity in polymers

  • Articles
  • Published:
Journal of Low Temperature Physics Aims and scope Submit manuscript

Abstract

We have measured the long time (t = 5 to 200 h) heat release of Polymethylmethacrylate (PMMA) and Polystyrene (PS) at 70 mK ⩽T ⩽ 300 mK. After cooling from a “charging” temperature of 80 K the heat release in PMMA shows a t−1 dependence in the measured time and temperature ranges in agreement with the tunneling model. In contrast, for PS we observe strong deviations from at −1 dependence and a factor of ten smaller heat release than in PMMA in apparent contradiction to specific heat and thermal conductivity data for PS. To compare the heat release with other low temperature properties and to verify the consistency of the tunneling model we have measured also the acoustical properties (sound velocity and attentuation), the specific heat and the thermal conductivity of PMMA and PS in the temperature range 70mK⩽T⩽ 100 mK, 70mK⩽T⩽200 mK and 0.3 K⩽T⩽4K, respectively. We show that the anomalous time dependence of the heat release of PS is due to the thermally activated relaxation of energy states with excitation energies above 15 K.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. J. Zimmerman and G. Weber,Phys. Rev. Lett. 46, 661 (1981).

    Google Scholar 

  2. M. Schwark, F. Pobell, M. Kubota, and R. M. Mueller,J. Low. Temp. Phys. 58, 171 (1985).

    Google Scholar 

  3. S. Sahling, A. Sahling, and M. Kolác,Solid State Commun. 65, 1031 (1988).

    Google Scholar 

  4. P. W. Anderson, B. I. Halperin, and C. M. Varma,Phil. Mag. 25, 1 (1972); W. A. Phillips,J. Low Temp. Physics 7, 351 (1972).

    Google Scholar 

  5. M. Deye and P. Esquinazi,Z. Phys. B — Condensed Matter76, 283 (1989).

    Google Scholar 

  6. M. Deye and P. Esquinazi, inPhonon 89, Eds. S. Hunkliner, W. Ludwig, abd G. Weiss (World Scientific, Singapore, 1990), p. 468.

    Google Scholar 

  7. J. Jäckle,Z. Phys. 257, 212 (1972).

    Google Scholar 

  8. D. Parshin and S. Sahling,Phys. Rev. B 47, 5677 (1993).

    Google Scholar 

  9. J. J. Brey and A. Prados,Phys. Rev. B 43, 8350 (1991).

    Google Scholar 

  10. P. Esquinazi, M. Scherl, Li Junyung, and F. Pobell, 4th International Conference on Phonon Scattering in Condensed Matter, Springer Series in Solid State Sciences Vol. 112, Eds. Meissner and Pohl, p. 287 (1993).

  11. D. Tielbürger, R. Merz, R. Ehrenfels, and S. Hunklinger,Phys. Rev. B 45, 2750 (1992).

    Google Scholar 

  12. P. Doussineau, C. Frenois, R. G. Leisure, A. Levelut, and J. Y. Prieur,J. Phys. (Paris)41, 1193 (1980).

    Google Scholar 

  13. S. Hunklinger and W. Arnold, inPhysical Acoustics, W. P. Mason, R. N. Thurston (eds.), Vol. XII, New York: Academic Press 1976.

    Google Scholar 

  14. W. A. Phillips inPhonon 89, Eds. S. Hunklinger, W. Ludwig, and G. Weiss (World Scientific, Singapore, 1990), p. 367.

    Google Scholar 

  15. K.-P. Müller and D. Haarer,Phys. Rev. Lett. 66, 2344 (1991).

    Google Scholar 

  16. A. K. Raychaudhuri and S. Hunklinger,Z. Phys. B — Condensed Matter57, 113 (1984).

    Google Scholar 

  17. R. B. Stephens,Phys. Rev. B 8, 2896 (1973).

    Google Scholar 

  18. R. B. Stephens, G. S. Cieloszyk, and G. L. Salinger,Phys. Lett. 28A, 215 (1972).

    Google Scholar 

  19. D. Cahill and R. Pohl,Phys. Rev. B 35, 4067 (1987).

    Google Scholar 

  20. C. Choy, G. Salinger, and Y. Chiang,J. of Applied Physics 41, 597 (1970).

    Google Scholar 

  21. J. Freeman and A. C. Anderson,Phys. Rev. B 34, 5684 (1986).

    Google Scholar 

  22. J. Mack, J. Freeman, and A. C. Anderson,J. of Non Crystalline Solids 91, 391 (1987).

    Google Scholar 

  23. G. Hartwig,Progr. Colloid and Polymer Sci. 64, 56 (1978).

    Google Scholar 

  24. G. Federle and S. Hunklinger,J. de Physique, C9 (12), Tome 43, p. C9-505 (1982). G. Federle, Doctoral Thesis, M. Planck Stuttgart, 1983, unpublished. A. K. Raychaudhuri inNon-Debye Relaxation in Condensed Matter, World Scientific, Eds. T. V. Ramakrishnan and M. Raj Lakshmi, p. 193 (1987).

  25. J. Crissman, J. Sauer, and E. Woodward,J. of Polymer Science A 2, 5075 (1964).

    Google Scholar 

  26. G. Bellesa,Phys. Rev. Lett. 40, 1456 (1978).

    Google Scholar 

  27. J.-Y. Duquesne and G. Bellesa,J. de Physique Lettres 40, L-193 (1979).

    Google Scholar 

  28. R. Nava and R. Oentrich,J. of Alloys and Compounds, to be published, R. Nava,Phys. Rev. B 49, 4295 (1994).

  29. P. Esquinazi, B. Neppert, and R. König, to be published.

  30. W. Köhler, J. Zollfrank, and J. Friedrich,Phys. Rev. B 39, 5414 (1989).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nittke, A., Scherl, M., Esquinazi, P. et al. Low temperature heat release, sound velocity and attenuation, specific heat and thermal conductivity in polymers. J Low Temp Phys 98, 517–547 (1995). https://doi.org/10.1007/BF00752280

Download citation

  • Received:

  • Revised:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00752280

Keywords

Navigation