Summary
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1.
A study has been made of binary mixtures consisting of a straight-chain alkane and a straight-chain 1-alkene with the same number of carbon atoms per molecule (from 8 to 18 inclusive); it has been established that the ULA for urea adducts with the primary component of these mixtures (straight-chain alkane) varies linearly with the mass concentration of the second component (straight-chain alkene) and can be described by the equationθ bin=θ — C·Δt.
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2.
For each pair of hydrocarbons investigated, constant gradients Δt have been determined over a range of mass concentrations of the second component from 0 to 99%.
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3.
Nomograms have been constructed for the graphical determination of gradients Δt for mixtures with n=7–9 and n=10–18.
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T. A. Volkova, I. D. Makhinya, et al., Khim. Tekhnol. Topl. Masel, No. 2, 14 (1975).
V. A. Matishev, Khim. Tekhnol. Topl. Masel, No. 11, 18–22 (1966).
V. A. Matishev, Khim. Tekhnol. Topl. Masel, No. 3, 19 (1968).
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Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 5, pp. 25–27, May, 1976.
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Matishev, V.A., Krupina, A.A. Upper limit of urea adduct formation with binary mixtures of straight-chain alkane and 1-alkene with same number of carbon atoms per molecule. Chem Technol Fuels Oils 12, 359–361 (1976). https://doi.org/10.1007/BF00717931
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DOI: https://doi.org/10.1007/BF00717931