Abstract
The destruction ofB-polyfluorosubstitutedo-carboranes by the action of ethanolic alkali and amines was studied. The destraction of trifluoro-o-carborane was found to occur regioselectively. The nature of the amine was shown to affect the stereochemistry of the destruction of trifluoro-o-carborane. The intermediate of the reaction of tetrafiuoro-o-carborane with diethylamine was detected.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1141–1145, June, 1995.
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Lebedev, V.N., Balagurova, E.V. & Zakharkin, L.I. Destruction ofB-polyfluorosubstitutedo-carboranes into anions ofB-fluorosubstitutednido-7,8-dicarbaundecaborates by the action of ethanolic alkali and amines. Russ Chem Bull 44, 1102–1106 (1995). https://doi.org/10.1007/BF00707062
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DOI: https://doi.org/10.1007/BF00707062