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Preparation and reactivity of metal containing monomers

42. Copolymerization of metal containing monomers as a route for the synthesis of the precursors of high temperature superconducting ceramics

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Abstract

The preparation of HTSC ceramics based on YIII and BiIII was studied. The polymers were obtained by two methods: by the reaction of preliminarily synthesized polyacrylic acid (PAA) or polyacrylamide (PAAm) with YIII, BaII, and CuII nitrates or by copolymerization of metal containing monomers (metal (YII, BaII, and CuII) acrylates or acrylamide complexes of metal (BiIII, CaII, SrII, PbII, and CuII) nitrates). The copolymerization was carried out in solution, in the solid phase, or using spontaneous polymerization, which has been previously discovered by the authors. The properties of the HTSC ceramics obtained are improved when the products of copolymerization of metal containing monomers are used.

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References

  1. J. C. W. Chien, B. M. Gong, J. M. Madsen, and R. B. Hallock,Phys. Rev., 1988,38B, 11853.

    Google Scholar 

  2. J. C. W. Chien, B. M. Gong, X. Mu, and Y. Yang,J. Polym. Sci.: Polym. Chem. Ed., 1990,29, 1993.

    Google Scholar 

  3. I. Valente, C. Sanchez, M. Henry, and J. Livage,Ind. Ceram., 1989, 1193.

  4. A. D. Pomogailo,Polimernye immobilizovannye metallokompleksnye katalizatory [Polymeric Immobilized Metal-Complex Catalysts], Nauka, Moscow, 1988, 303 pp. (in Russian).

  5. A. D. Pomogailo and V. S. Savost'yanov,Metallsoderzhashchie monomery i polimery na ikh osnove [Metal containing Monomers and Polymers Based on Them], Khimiya, Moscow, 1988, 384 pp. (in Russian).

  6. G. I. Dzhardimalieva, A. D. Pomogailo, V. I. Ponomarev, L. O. Atovmyan, Yu. M. Shul'ga, and A. G. Starikov,Izv. Akad. Nauk SSSR, Ser. Khim., 1988, 1525 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1988,37, 1346 (Engl. Transl.)].

    Google Scholar 

  7. V. S. Savost'yanov, V. N. Vasilets, O. V. Ermakov, E. A. Sokolov, A. D. Pomogailo, D. A. Kritskaya, and A. N. Ponomarev,Izy. Akad. Nauk SSSR, Ser. Khim., 1992, 2073 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1992,40, 1615 (Engl. Transl.)].

    Google Scholar 

  8. A. V. Dubovitskii, E. F. Makarov, M. K. Makova, V. A. Merzhanov, and V. N. Topnikov,Sverkhprovodimost':fizika, khimiya, tekhnika [Superconductivity: Chemistry, Physics, Engineering], 1991,4, 1024 (in Russian).

    Google Scholar 

  9. M. R. Chanrachood, S. R. Sinkaz, I. S. Mulla, and S. Badzinazayanan,Material Lett., 1989,8, 349.

    Google Scholar 

  10. Ya. E. Geguzin,Fizika spekaniya [Physics of Sintering], Nauka, Moscow, 1984, 312 pp. (in Russian).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Chemical Physics in Chernogolovka, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    A. D. Pomogailo, G. I. Dzhardimalieva & A. V. Dubovitskii

  2. Branch of the Institute of Energetic Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow Region, Russian Federation

    V. S. Savost'yanov & A. N. Ponomarev

Authors
  1. A. D. Pomogailo
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  2. V. S. Savost'yanov
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  3. G. I. Dzhardimalieva
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  4. A. V. Dubovitskii
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  5. A. N. Ponomarev
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Additional information

For part 41, seeIzv. Akad. Nauk, Ser. Khim., 1995, 885 [Russ. Chem. Bull., 1995,44, 858 (Engl. Transl.)].

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1096–1101, June, 1995.

The authors wish to thank V. N. Topnikov and M. K. Makova for measuring the characteristics of HTSC ceramics and V. A. Zhorin for conducting copolymerization of metal containing monomers under high pressures combined with shear strains.

The work was carried out with financial support of the International Science Foundation (Grant NJB 000).

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Pomogailo, A.D., Savost'yanov, V.S., Dzhardimalieva, G.I. et al. Preparation and reactivity of metal containing monomers. Russ Chem Bull 44, 1056–1061 (1995). https://doi.org/10.1007/BF00707052

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  • DOI: https://doi.org/10.1007/BF00707052

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