Abstract
Weak bases such as 2-aminopyridine, 4-aminopyridine,o-phenylenediamine,p-phenylenediamine and aniline were intercalated into aluminium dihydrogentriphosphate (ADHP) using ultrasonic wave irradiation. The interlayer spacing of ADHP increased from 8.1 Å to 12.4–20.0 Å. From the values of the layer expansions and host/guest ratios, bilayer or monolayer structures were considered. Chemical oxidation of the aniline resulted in the formation of polyaniline in the ADHP layers.
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Tagaya, H., Sato, S., Kuramoto, N. et al. Intercalation chemistry of aluminium dihydrogentriphosphate with weak bases and polymerization of aniline between its layers. Journal of Inclusion Phenomena and Molecular Recognition in Chemistry 18, 193–204 (1994). https://doi.org/10.1007/BF00705821
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DOI: https://doi.org/10.1007/BF00705821