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Membrane catalysts for hydrogenation with cryochemically synthesized palladium clusters

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Abstract

New type of membrane catalysts has been prepared through blinding of 2–3 µm pores of cermet membranes with Pd clusters from its cryochemically synthesized sol in toluene. Those catalysts display 30 times superior activity with respect to Pd weight than the membrane catalysts in the form of foil from Pd alloys.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organo Element Compounds, Academy of Sciences of the USSR, 28 Vavilov Str., 117813, Moscow, USSR

    Alexander Yu. Vasil'kov, Andrei Yu. Olenin & Vladimir A. Sergeev

  2. A. V. Topchiev Institute of Petrochemical Synthesis, Academy of Sciences of USSR, 29 Leninski prosp., 117912, Moscow, USSR

    Andrei N. Karavanov, Elena G. Olenina & Vladimir M. Gryaznov

Authors
  1. Alexander Yu. Vasil'kov
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  2. Andrei Yu. Olenin
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  3. Vladimir A. Sergeev
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  4. Andrei N. Karavanov
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  5. Elena G. Olenina
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  6. Vladimir M. Gryaznov
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Vasil'kov, A.Y., Olenin, A.Y., Sergeev, V.A. et al. Membrane catalysts for hydrogenation with cryochemically synthesized palladium clusters. J Clust Sci 2, 117–119 (1991). https://doi.org/10.1007/BF00702952

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  • DOI: https://doi.org/10.1007/BF00702952

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