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Synthesis and structure of novel derivatives of thieno[2,3-b]thiocine. An unusual product of intramolecular cycloaddition of 2-homomethallylthio-5-methyl-3-thiophenecarbonitrile oxide

  • Organic Chemistry
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Russian Chemical Bulletin Aims and scope

Abstract

9-Methyl-3,3a,4,5-tetrahydro-6H-thieno[2,3-b]thiocino[4,5-c]isoxazole and 9-hydroxyimino-2-methyl-7-methylene-6, 7,8,9-tetrahydro-5H-thieno[2,3-b]thiocine have been prepared for the first time by the oxidation of 2-ω-alkenylthio-3-thiophenecarbaldoximes with NaOCl. X-ray structural investigations of thieno[2,3-b]thiocine and 2-homomethallylthio-5-methyl-3-thiophenecarbaldoxime have been carried out.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    M. M. Krayushkin, M. A. Kalik, L. G. Vorontsova, E. Yu. Zvezdina & M. G. Kurella

Authors
  1. M. M. Krayushkin
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  2. M. A. Kalik
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  3. L. G. Vorontsova
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  4. E. Yu. Zvezdina
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  5. M. G. Kurella
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1262–1266, July, 1993.

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Krayushkin, M.M., Kalik, M.A., Vorontsova, L.G. et al. Synthesis and structure of novel derivatives of thieno[2,3-b]thiocine. An unusual product of intramolecular cycloaddition of 2-homomethallylthio-5-methyl-3-thiophenecarbonitrile oxide. Russ Chem Bull 42, 1204–1208 (1993). https://doi.org/10.1007/BF00702007

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  • DOI: https://doi.org/10.1007/BF00702007

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