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Synthesis and structure of tricyclic furanosesquiterpenoids related to pallescensin A

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Abstract

Electrophilic cyclization of (cyclo)farnesanes containing anexo-methylene group in the a-isoprenoid unit smoothly gives regio- and stereoisomeric octalins subsequently transformed to tricyclic furanosesquiterpenoids related to metabolites of some marine organisms.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913, Moscow, Russian Federation

    A. M. Moiseenkov, A. V. Lozanova, A. A. Surkova, V. A. Dragan, Yu. A. Strelenko & A. V. Buevich

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  1. A. M. Moiseenkov
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  2. A. V. Lozanova
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  3. A. A. Surkova
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  4. V. A. Dragan
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  5. Yu. A. Strelenko
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  6. A. V. Buevich
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Additional information

Deceased.

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 156–163, January, 1994.

The authors are grateful to the representative of the Bruker company in Moscow, Uve Eichhof, who allowed us to use an AMX-400 spectrometer.

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Moiseenkov, A.M., Lozanova, A.V., Surkova, A.A. et al. Synthesis and structure of tricyclic furanosesquiterpenoids related to pallescensin A. Russ Chem Bull 43, 153–160 (1994). https://doi.org/10.1007/BF00699157

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  • DOI: https://doi.org/10.1007/BF00699157

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