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2-(Methylthio)pentafluoropropene

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Abstract

2-(Methylthio)pentafluoropropene was obtained by dehydrofluorination of methyl 2H-hexafluoroisopropyl sulfide by the BF3 · NEt3 complex. Its reactivity with respect to allyl alcohol and hexamethyldisilazane was studied. The electrophilicity of 2-(methylthio)penta-fluoropropene was compared with the properties of terminal polyfluoroalkenes whose behavior in these reactions has been studied previously.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813, Moscow, Russian Federation

    V. G. Andreev, A. Yu. Sizov & A. F. Kolomiets

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  1. V. G. Andreev
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  2. A. Yu. Sizov
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  3. A. F. Kolomiets
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Additional information

Perfluoroisobutylene also reacts with allyl alcohol in the absence of protophilic agents.3,4

Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 80–84, January, 1994.

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Andreev, V.G., Sizov, A.Y. & Kolomiets, A.F. 2-(Methylthio)pentafluoropropene. Russ Chem Bull 43, 75–79 (1994). https://doi.org/10.1007/BF00699139

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  • DOI: https://doi.org/10.1007/BF00699139

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