Abstract
The iridium hydride complex HIr(CO)(PPh3)3 reacts with fullerenes C60 and C70 yielding (η2-Cn)IrH(CO)(PPh3)2 (n = 60, 70) complexes. Their composition, configuration, and the position of the double bond coordinated with the metal atom in the fullerene moiety have been established by IR studies (comparison with deuterated analogs), and1H and31P NMR spectroscopy.
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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1661–1665, September, 1994.
The present work was financialy supported by the Russian Foundation for Basic Research (Project No. 93-09-18725) and the International Science Foundation (Project No. MNR 000).
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Usatov, A.V., Vorontsov, E.V., Vinogradova, L.E. et al. Organometallic hydrides as reactants in fullerene chemistry. Interaction of C60 and C70 fullerenes with HIr(CO)(PPh3)3 . Russ Chem Bull 43, 1572–1576 (1994). https://doi.org/10.1007/BF00697152
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DOI: https://doi.org/10.1007/BF00697152