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Synthesis of hydroxyphosphoranes from triphenylphosphine and triphenylphosphine oxide

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Abstract

Novel hydroxyphosphoranes were synthesized using the oxidative method from triphenylphosphine, 1,1′-dihydroxydicyclohexyl, benzopinacol, and aminophenol in the presence oftert-butyl hydroperoxide. Hydroxyphosphoranes were also obtained from triphenylphosphine oxide, and the series of dihydric phenols and diols mentioned above.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1779–1781, October, 1993.

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Dodonov, V.A., Zaburdyaeva, S.N. & Fominskii, D.G. Synthesis of hydroxyphosphoranes from triphenylphosphine and triphenylphosphine oxide. Russ Chem Bull 42, 1703–1705 (1993). https://doi.org/10.1007/BF00697045

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  • DOI: https://doi.org/10.1007/BF00697045

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