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Synthesis of novel spin-labeled crown ethers

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Abstract

Diazonium salts obtained from aminophenyl-substituted crown ethers react with paramagnetic imidazolinium salt to yield arylazoenamines, containing spin-labeled crown ethers. An alternative approach to the synthesis of related compounds, spin-labeled ureas, consists of the reaction of aminophenyl-substituted crown ethers with paramagnetic isocyanates.

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Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1770–1772, October, 1993.

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Reznikov, V.A., Berezina, T.A., Volodarskii, L.B. et al. Synthesis of novel spin-labeled crown ethers. Russ Chem Bull 42, 1694–1696 (1993). https://doi.org/10.1007/BF00697042

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  • DOI: https://doi.org/10.1007/BF00697042

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