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A new modification of silicon obtained under the effect of explosion

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Abstract

Condensed products of explosion of mixtures containing lead and silicon are investigated by x-ray phase, electron microscopic, x-ray spectral, and chemical methods. The exploded mixtures were based on tetrazene or hexogen. The mass content of silicon in the mixtures was 20%. The explosion was initiated by lead azide with a mass of 0.1 g. The condensed products of the explosion contained a solid solution of lead-silicon based on Pb(I), a new modification of silicon with a face-centered cubic lattice witha = 5.935±0.002 Å, and exhibited heteroepitaxy.

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Translated from Steklo i Keramika, No. 9, pp. 22–25, September, 1995.

The authors are deeply grateful to Professor L. M. Kovba for his valuable comments in the discussion of this work.

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Tsvigunov, A.N., Khotin, V.G., Kuznetsov, S.E. et al. A new modification of silicon obtained under the effect of explosion. Glass Ceram 52, 245–248 (1995). https://doi.org/10.1007/BF00681092

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