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On-off-switched crown-metal complexation by photoinduced intramolecular tail (ammonium)-biting

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Abstract

New photoresponsive crown ethers (1H+) having a crown ring and an ammoniumalkyl (H3N+(CH2)n −, n=4,6,10) group attached to the two sides of an azobenzene have been synthesized. Photoresponsive properties (thermal isomerization, metal extraction, membrane transport, etc.) were examined, and the results were compared with those of other photoresponsive crown ethers and complexons.

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References

  1. S. Shinkai, and O. Manabe, ‘Host-Guest Complex Chemistry III’, Springer-Verlag, Berlin, 1984, p 67.

    Google Scholar 

  2. S. Shinkai, T. Nakaji, T. Ogawa, K. Shigematsu and O. Manabe,J. Am. Chem. Soc.,103, 111 (1981).

    Google Scholar 

  3. S. Shinkai, K. Shigematsu, Y. Kusano, and O. Manabe,J. Chem. Soc., Perkin Trans. 1, 1981, 3279.

    Google Scholar 

  4. S. Shinkai, M. Nakashima, S. Nakamura, and O. Manabe, to be submitted.

  5. S. Shinkai, T. Ogawa, Y. Kusano, O. Manabe, K. Kikukawa, T. Goto, and T. Matsuda,J. Am. Chem. Soc.,104, 1960 (1982).

    Google Scholar 

  6. S. Shinkai, K. Shigematsu, M. Sato, and O. Manabe,J. Chem. Soc., Perkin Trans. 1, 1982, 2735.

    Google Scholar 

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Authors and Affiliations

  1. Department of Industrial Chemistry Faculty of Engineering, Nagasaki University, 852, Nagasaki, Japan

    S. Shinkai, M. Ishihara, K. Ueda & O. Manabe

Authors
  1. S. Shinkai
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  2. M. Ishihara
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  3. K. Ueda
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  4. O. Manabe
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Shinkai, S., Ishihara, M., Ueda, K. et al. On-off-switched crown-metal complexation by photoinduced intramolecular tail (ammonium)-biting. Journal of Inclusion Phenomena 2, 111–118 (1984). https://doi.org/10.1007/BF00663246

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  • DOI: https://doi.org/10.1007/BF00663246

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