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Metal Crown-Porphyrin Complexes: Preparation, Optical Properties, and Applications (Review)

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Abstract

The review addresses methods for the synthesis of metal complexes of crown-substituted porphyrins; structural features of these compounds; and the influence of metal cations on the luminescence and other photophysical properties of metal crown-porphyrin complexes. Thermochromic, fluorescence, and phosphorescence properties of metal crown-porphyrins are analyzed; the applicability of these compounds as luminescence-based temperature sensors, sensors for alkali metal cations, thermochromic materials, and active components of photovoltaic energy converters are considered.

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Funding

The review was supported by the Russian Foundation for Basic Research (project no. 19-13-50112 “Expansion”).

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. Yu. Tsivadze & A. Yu. Chernyad’ev

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  1. A. Yu. Tsivadze
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Translated by Z. Svitanko

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Tsivadze, A.Y., Chernyad’ev, A.Y. Metal Crown-Porphyrin Complexes: Preparation, Optical Properties, and Applications (Review). Russ. J. Inorg. Chem. 65, 1662–1686 (2020). https://doi.org/10.1134/S0036023620110194

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