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Light scattering in binary and ternary (polymer) solutions with specific interactions

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Abstract

Concentration dependence of basic light-scattering quantities in three binary low-molecular and two ternary polymer solutions was studied. Depolarization ratio alone may serve as a sensitive measure of presence of specific interactions. Experimental data of anisotropic scattering in low-molecular mixtures were in harmony with the idea that the parameters determining molecular orientation should be considered as continuous probability variables; in the case of polymer solutions specific interactions do not influence the anisotropic scattering.

The presence of specific interactions with the formation of a minimum on the course of isotropic scattering is characterized. Transition from one solution structure to another with a local maximum on the course of composition light scattering is indicated.

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References

  1. Adelman RL, Klein J (1958) J Polymer Sci 31:77

    Google Scholar 

  2. Dondos A (1972) Makromol Chem 162:113

    Google Scholar 

  3. Coumou DJ, Hijmans J, Mackor EL (1964) Trans Faraday Soc 60:2244

    Google Scholar 

  4. Kerker M (1969) The scattering of light and other electromagnetic radiation. Academic Press, New York

    Google Scholar 

  5. Shakhparonov MI (1973) Physics and Physical Chemistry of Liquids, 2nd edition (in Russian) Izd MGU Moscow

  6. Beke Gy, Keszei E (1980) Acta Chim Acad Sci Hung 104:363

    Google Scholar 

  7. Vavra J, Danciger J (1981) Chem Papers 35:441

    Google Scholar 

  8. Kumar R, Prausnitz JM (1975) In: Dack MRJ (ed) Solutions and Solubilities Part I. J Wiley & Sons, New York, p 259

    Google Scholar 

  9. Balachandran CJ (1954) J Indian Inst Sci 36:10

    Google Scholar 

  10. Vavra J, Rosenbergerová A (1979) Z Phys Chem Leipzig 260:1073

    Google Scholar 

  11. Iwasaki K, Tanaka M, Fujiyama T (1976) Bull Chem Jap 49:2719

    Google Scholar 

  12. Kato T, Fujiyama T (1976) J Phys Chem 80:2771

    Google Scholar 

  13. Sedláček B, Kratochvil P, Straková D (1972) Collect Czechoslov Chem Commun 37:970

    Google Scholar 

  14. Fujiskige S, Elias LG (1972) Makromol Chemie 155:127

    Google Scholar 

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  1. J. Vavra

    Present address: Department of Physical Chemistry, Slovak Technical University, CS-81237, Bratislava, CSFR

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    1. J. Vavra
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    Vavra, J. Light scattering in binary and ternary (polymer) solutions with specific interactions. Colloid Polym Sci 271, 480–485 (1993). https://doi.org/10.1007/BF00657392

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    • DOI: https://doi.org/10.1007/BF00657392

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