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Synthesis and characterization of emulsifier-free quaternarized vinylbenzylchloride latexes

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Abstract

Polycationic polymers have been obtained through a two-step procedure. First, poly-vinylbenzylchloride [P(VBC)] latexes were prepared under emulsifier-free conditions using a cationic initiator: 2,2′-azobis(2-amidinopropane) hydrochloride; then the resulting latexes were reacted with trimethylamine. Particular attention was paid to side reactions occurring during the hydrolysis of the chloromethyl groups and the crosslinking reaction due to a transfer reaction onto polymer. The influence of various parameters on the particle size and structure of latexes as well as secondary reactions were investigated through a careful characterization.

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Author notes

  1. B. Verrier-Charleux & C. Pichot

    Present address: Unité Mixte CNRS/Biomerieux, ENSL, Lyon, France

Authors and Affiliations

  1. CNRS-Laboratoire des Materiaux Organiques, BP 24, 69390, Vernaison, France

    B. Verrier-Charleux, C. Graillat, Y. Chevalier, C. Pichot & A. Revillon

Authors
  1. B. Verrier-Charleux
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  2. C. Graillat
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  3. Y. Chevalier
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  4. C. Pichot
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  5. A. Revillon
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Verrier-Charleux, B., Graillat, C., Chevalier, Y. et al. Synthesis and characterization of emulsifier-free quaternarized vinylbenzylchloride latexes. Colloid Polym Sci 269, 398–405 (1991). https://doi.org/10.1007/BF00654586

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  • DOI: https://doi.org/10.1007/BF00654586

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