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Isotope effects in aqueous systems. X. Boiling point elevations for NaCl solutions in H2O and D2O

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Abstract

Solvent isotope effects on the osmotic coefficients of NaCl solutions in H2O or D2O have been determined by an ebulliometric technique at 100°C.

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References

  1. H. L. Friedman and C. V. Krishnan inWater, A Comprehensive Treatise, Vol. 3. F. Franks, ed. (Plenum Press, New York, 1973), p. 1.

    Google Scholar 

  2. G. Jancso and W. A. Van Hook,Chem. Reviews 74, 689 (1974).

    Google Scholar 

  3. Q. C. Craft and W. A. Van Hook,J. Solution Chem. 4, 923 (1975).

    Google Scholar 

  4. J. Pupezin, G. Jakli, G. Jancso, and W. A. Van Hook,J. Phys. Chem. 76, 743 (1972).

    Google Scholar 

  5. Q. C. Craft and W. A. Van Hook,J. Solution Chem. 4, 901 (1975).

    Google Scholar 

  6. G. Dessauges, N. Miljevic, and W. A. Van Hook,J. Phys. Chem. 84, 2587 (1980).

    Google Scholar 

  7. B. E. Conway and L. H. LaLiberte,Trans. Faraday Soc. 66, 3032 (1970).

    Google Scholar 

  8. J. L. Fortier, P. R. Philip, and J. E. Desnoyers,J. Solution Chem. 3, 523 (1974).

    Google Scholar 

  9. J. G. Mathison and B. E. Conway,Trans. Faraday Soc. 70, 752 (1974).

    Google Scholar 

  10. R. P. Smith,J. Am. Chem. Soc. 61, 497 (1939).

    Google Scholar 

  11. G. N. Lewis, M. Randall, K. S. Pitzer, and L. Brewer,Thermodynamics (McGraw Hill, New York, 1961), p. 406.

    Google Scholar 

  12. D. D. Ensor and H. L. Anderson,J. Chem. Eng. Data 18, 205 (1973).

    Google Scholar 

  13. R. A. Robinson and R. H. Stokes,Electrolyte Solutions, 2nd edn. (Academic Press, New York, 1959).

    Google Scholar 

  14. R. P. Smith and D. S. Hirtle,J. Am. Chem. Soc. 61, 1123 (1939).

    Google Scholar 

  15. H. S. Harned and B. B. Owen,The Physical Chemistry of Electrolytic Solutions, 3rd edn. (Rheinhold, New York, 1955).

    Google Scholar 

  16. B. R. Staples and R. L. Nuttall,J. Phys. Chem. Ref. Data 6, 385 (1977).

    Google Scholar 

  17. R. N. Goldberg and R. L. Nuttall,J. Phys. Chem. Ref. Data 7, 263 (1978).

    Google Scholar 

  18. K. S. Pitzer,Accounts of Chem. Research 10, 371 (1977) and references cited therein.

    Google Scholar 

  19. N. R. Miljevic, Thesis, University of Belgrade (1979).

  20. G. Dessauges and W. A Van Hook,J. Inorganic and Nuclear Chem., in press.

  21. G. A. Vidulich, D. F. Evans, and R. L. Kay,J. Phys. Chem. 71, 656 (1967).

    Google Scholar 

  22. G. S. Kell,J. Chem. Eng. Data 12, 66 (1967).

    Google Scholar 

  23. M. K. Dutta-Choudhury and W. A. Van Hook,J. Phys. Chem. 84, 2735 (1980).

    Google Scholar 

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Miljevic, N., Dessauges, G. & Van Hook, W.A. Isotope effects in aqueous systems. X. Boiling point elevations for NaCl solutions in H2O and D2O. J Solution Chem 10, 29–38 (1981). https://doi.org/10.1007/BF00652778

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  • DOI: https://doi.org/10.1007/BF00652778

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