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Enthalpies of proton transfer of amines in methanol-water mixtures by direct calorimetry

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Abstract

Enthalpies of proton transfer in methanol-water mixtures (0–90 wt.% methanol) have been measured by direct calorimetry for the bases quinuclidine, triethylamine, t-butylamine and tris(hydroxymethyl)aminomethane. The results are discussed in terms of an adaptation of classical electrostatic formula.

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Sankar, M., Bayles, J.W. Enthalpies of proton transfer of amines in methanol-water mixtures by direct calorimetry. J Solution Chem 22, 1099–1108 (1993). https://doi.org/10.1007/BF00651692

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  • DOI: https://doi.org/10.1007/BF00651692

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