Skip to main content
SpringerLink
Log in

Enthalpies of Glycine Protonation in Water–Acetone and Water–Ethanol Solvents

  • PHYSICAL CHEMISTRY OF SOLUTIONS
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

Heat effects of the reaction of glycine protonation  at  298 K  in  water–ethanol  (µ = 0.1 (NaClO4)) and water–acetone (µ = 0.3 (NaClO4)) solvents of various compositions are determined via calorimetry. The enthalpies of the resolvation of glycinium ions in aqueous solutions of ethanol and acetone are calculated using the literature data. It is established that a minor change in the heat effect of the reaction of glycine protonation in water–ethanol and water–acetone solvents is associated with the mutual compensation of the enthalpies of proton, glycinium-ion, and glycine resolvation in these media. It is shown that the contribution from the enthalpy component to the change in the Gibbs energy of this reaction is insignificant.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. V. A. Isaeva, S. F. Ledenkov, V. A. Sharnin, and V. A. Shormanov, Zh. Fiz. Khim. 67, 2202 (1993).

    CAS  Google Scholar 

  2. V. A. Isaeva, N. V. Ganicheva, and V. A. Sharnin, Russ. J. Phys. Chem. A 76, 1953 (2002).

    Google Scholar 

  3. V. A. Isaeva, V. A. Sharnin, V. A. Shormanov, and I. A. Baranova, Russ. J. Phys. Chem. A 70, 1232 (1996).

    Google Scholar 

  4. V. A. Isaeva, G. I. Repkin, Zh. F. Gesse, and V. A. Sharnin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 57 (3), 49 (2014).

    CAS  Google Scholar 

  5. V. A. Isaeva and V. A. Sharnin, Russ. J. Phys. Chem. A 92, 214 (2018).

    Article  CAS  Google Scholar 

  6. S. V. Semenovskii, G. A. Krestov, and V. A. Kobenin, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 15, 1257 (1972).

    CAS  Google Scholar 

  7. V. P. Vasil’ev, V. A. Borodin, and E. V. Kozlovskii, Applications of Computers in Analytical Chemistry Calculations (Vyssh. Shkola, Moscow, 1993) [in Russian].

    Google Scholar 

  8. E. M. Woollej, D. G. Hurkot, and L. G. Hepler, J. Phys. Chem. 74, 3908 (1970).

    Article  Google Scholar 

  9. Syntheses of Organic Preparations, Collection of Articles, Ed. by B. A. Kazanskii (Inostr. Liter., Moscow, 1949) [in Russian].

    Google Scholar 

  10. S. R. Palit, M. N. Das, and G. R. Somayajulu, Non-Aqueous Titrations (IACA, Calcutta, 1954; Goskhimizdat, Moscow, 1985).

  11. V. P. Vasil’ev, N. K. Grechina, and I. Yu. Korotkova, in Thermodynamics and Solution Structure, Collection of Articles (Ivanovo, 1979), p. 83 [in Russian].

    Google Scholar 

  12. V. P. Vasil’ev and L. A. Kochergina, Zh. Obshch. Khim. 49, 2042 (1979).

    Google Scholar 

  13. B. J. Sturtenvant, J. Am. Chem. Soc. 63, 88 (1941).

    Article  Google Scholar 

  14. H. Gao, X. Hu, and R. Lin, Thermochim. Acta 346, 1 (2000).

    Article  CAS  Google Scholar 

  15. A. V. Nishchenkov, V. A. Sharnin, V. A. Shormanov, and G. A. Krestov, Zh. Fiz. Khim. 64, 114 (1990).

    CAS  Google Scholar 

  16. L. A. Kochergina, A. V. Emel’yanov, and O. N. Krutova, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 55 (11), 28 (2012).

    CAS  Google Scholar 

  17. L. A. Kochergina, A. V. Emel’yanov, O. N. Krutova, and G. G. Gorboletova, Russ. J. Phys. Chem. A 81, 1632 (2007).

    Article  CAS  Google Scholar 

  18. N. N. Kuranova, S. V. Dushina, and V. A. Sharnin, Russ. J. Phys. Chem. A 84, 792 (2010).

    Article  CAS  Google Scholar 

  19. H. S. Harned and B. B. Owen, Physical Chemistry of Electrolytic Solutions (Chapman and Hall, London, 1950).

    Google Scholar 

  20. H. Gillet, Can. J. Chem. 68, 655 (1990).

    Article  CAS  Google Scholar 

  21. S. F. Ledenkov, V. A. Sharnin, and V. A. Isaeva, Zh. Fiz. Khim. 69, 994 (1995).

    CAS  Google Scholar 

  22. V. A. Sharnin, V. A. Shormanov, G. A. Krestov, and S. N. Pukhov, Zh. Neorg. Khim. 26, 24 (1981).

    CAS  Google Scholar 

  23. A. V. Nishchenkov, V. A. Sharnin, V. A. Shormanov, and G. A. Krestov, Zh. Fiz. Khim. 64, 114 (1990).

    CAS  Google Scholar 

  24. A. V. Nevskii, V. A. Shormanov, and G. A. Krestov, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 27, 155 (1984).

    CAS  Google Scholar 

  25. A. V. Nevskii, V. A. Shormanov, G. A. Krestov, and E. S. Pirogova, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 27, 730 (1984).

    CAS  Google Scholar 

  26. C. H. Sprink and M. Auker, J. Phys. Chem. 74, 1742 (1970).

    Article  Google Scholar 

  27. V. I. Smirnov, V. G. Badelin, and I. N. Mezhevoi, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. 46 (1), 90 (2003).

    CAS  Google Scholar 

  28. V. A. Sharnin, V. A. Shormanov, and G. A. Krestov, Zh. Fiz. Khim. 53, 600 (1979).

    CAS  Google Scholar 

  29. V. A. Shormanov, V. A. Sharnin, A. V. Nishchenkov, and G. A. Krestov, Koord. Khim. 9, 81 (1983).

    CAS  Google Scholar 

Download references

ACKNOWLEDGMENTS

This work was performed at the Scientific Research Institute of Thermodynamics and the Kinetics of Chemical Processes, Ivanovo State University of Chemistry and Technology.

Author information

Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    V. A. Isaeva & V. A. Sharnin

Authors
  1. V. A. Isaeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. A. Sharnin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Isaeva.

Additional information

Translated by L. Brovko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Isaeva, V.A., Sharnin, V.A. Enthalpies of Glycine Protonation in Water–Acetone and Water–Ethanol Solvents. Russ. J. Phys. Chem. 92, 2176–2181 (2018). https://doi.org/10.1134/S003602441811016X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S003602441811016X

Keywords:

Search

Navigation